Mechanochemical Release of N‐Heterocyclic Carbenes from Flex‐Activated Mechanophores
We have discovered a new flex‐activated mechanophore that releases an N‐heterocyclic
carbene (NHC) under mechanical load. The mechanophore design is based upon NHC …
carbene (NHC) under mechanical load. The mechanophore design is based upon NHC …
N-Heterocyclic carbene–carbodiimide (NHC–CDI) betaine adducts: synthesis, characterization, properties, and applications
N-Heterocyclic carbenes (NHCs) are an important class of reactive organic molecules used
as ligands, organocatalysts, and σ-donors in a variety of electroneutral ylide or betaine …
as ligands, organocatalysts, and σ-donors in a variety of electroneutral ylide or betaine …
N-Heterocyclic Carbene-Carbodiimide (NHC-CDI) Betaines as Organocatalysts for β-Butyrolactone Polymerization: Synthesis of Green PHB Plasticizers with Tailored …
The manufacture of poly (3-hydroxybutyrate)(PHB) stands out as a promising alternative to
traditional plastics. This polymer is usually produced by bacteria-based biotechnology or …
traditional plastics. This polymer is usually produced by bacteria-based biotechnology or …
Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts
LM Martínez-Prieto, I Cano, A Márquez… - Chemical …, 2017 - pubs.rsc.org
Ligand control of metal nanoparticles (MNPs) is rapidly gaining importance as ligands can
stabilize the MNPs and regulate their catalytic properties. Herein we report the first example …
stabilize the MNPs and regulate their catalytic properties. Herein we report the first example …
NHC-CDI Ligands Boost Multicarbon Production in Electrocatalytic CO2 Reduction by Increasing Accumulated Charged Intermediates and Promoting *CO …
Copper-based materials exhibit significant potential as catalysts for electrochemical CO2
reduction, owing to their capacity to generate multicarbon hydrocarbons. The molecular …
reduction, owing to their capacity to generate multicarbon hydrocarbons. The molecular …
Luminescent tetranuclear copper (I) and gold (I) heterobimetallic complexes: A phosphine acetylide amidinate orthogonal ligand framework for selective complexation
The synthesis of phosphine acetylide amidinate stabilized copper (I) and gold (I)
heterobimetallic complexes was achieved by reacting ligand [{Ph2PC≡ CC (NDipp) 2} Li …
heterobimetallic complexes was achieved by reacting ligand [{Ph2PC≡ CC (NDipp) 2} Li …
N-Heterocyclic Carbene–Carbodiimide (“NHC–CDI”) Adduct or Zwitterionic-Type Neutral Amidinate-Supported Magnesium (II) and Zinc (II) Complexes
A series of structurally characterized magnesium and zinc complexes of the form L4-t BuPh–
M {N (SiMe3) 2} 2 [M= Mg (1) and Zn (2); L4-t BuPh= 1, 3-diethyl-4, 5-dimethylimidazolium-2 …
M {N (SiMe3) 2} 2 [M= Mg (1) and Zn (2); L4-t BuPh= 1, 3-diethyl-4, 5-dimethylimidazolium-2 …
[HTML][HTML] The Structural Aspects of Mutually Trans-X-Cu (I)-X (X= OL, NL, CL, PL, SL, SeL, Cl or Br) Complexes
M Melník, V Mikušová, P Mikuš - Inorganics, 2024 - mdpi.com
The structural parameters for sixty mutually trans-(X-Cu (I)-X)(X= OL, NL, CL, PL, SL, SeL, Cl
or Br, where OL, NL, CL, PL, SL, and SeL are ligands L with respective donor atoms O, N, C …
or Br, where OL, NL, CL, PL, SL, and SeL are ligands L with respective donor atoms O, N, C …
Three Luminescent Copper (I) Iodide Clusters with Phosphine Ligands: Synthesis, Structure Characterization, Properties and TD-DFT Calculations
RE Shou, WX Chai, L Song, LS Qin, HS Shi… - Journal of Cluster …, 2017 - Springer
Three new luminescent copper (I) iodide complexes with their respective phosphine ligands,
namely [Cu (μ 2-I)(o-Anisyl 3 P)] 2· CH 3 CN (1),[Cu (μ 3-I)(m-Anisyl 3 P)] 4 (2) and [Cu (μ 3 …
namely [Cu (μ 2-I)(o-Anisyl 3 P)] 2· CH 3 CN (1),[Cu (μ 3-I)(m-Anisyl 3 P)] 4 (2) and [Cu (μ 3 …
Switchable Organocatalysis from N‐heterocyclic Carbene‐Carbodiimide Adducts with Tunable Release Temperature**
LD Pham, RO Smith‐Sweetser… - Angewandte Chemie …, 2023 - Wiley Online Library
N‐Heterocyclic carbenes (NHCs) are powerful organocatalysts, but practical applications
often require in situ generation from stable precursors that “mask” the NHC reactivity via …
often require in situ generation from stable precursors that “mask” the NHC reactivity via …