Ir-catalyzed proximal and distal C–H borylation of arenes

C Haldar, ME Hoque, J Chaturvedi… - Chemical …, 2021 - pubs.rsc.org
Over the past two decades, the C–H bond activation and functionalization reaction has been
known as a prevailing method for the construction of carbon–carbon and carbon …

Transient directing groups in metal− organic cooperative catalysis

C Jacob, BUW Maes, G Evano - Chemistry–A European …, 2021 - Wiley Online Library
The direct functionalization of C− H bonds is among the most fundamental chemical
transformations in organic synthesis. However, when the innate reactivity of the substrate …

para‐Selective C−H Borylation of Aromatic Quaternary Ammonium and Phosphonium Salts

S Lu, T Zheng, J Ma, Z Deng, S Qin… - Angewandte …, 2022 - Wiley Online Library
Aromatic ammonium and phosphonium salts are important synthetic intermediates and
multifunctional materials, but para‐selective functionalization of the aromatic salts remains a …

Electrostatically-directed Pd-catalysis in combination with C–H activation: site-selective coupling of remote chlorides with fluoroarenes and fluoroheteroarenes

WA Golding, RJ Phipps - Chemical science, 2020 - pubs.rsc.org
Systems incorporating catalyst–substrate non-covalent interactions are emerging as a
versatile approach to address site-selectivity challenges in remote functionalization …

Site-selective arene C–H functionalization by cooperative metal catalysis

Y Nakao - Bulletin of the Chemical Society of Japan, 2024 - academic.oup.com
Efforts made over the past 3 decades have led to the development of various organic
transformations that directly convert unfunctionalized C–H bonds into functional groups by …

Remote Regioselective Electrophilic Aromatic Substitutions Using a Tetrafluoropyridyl (TFP) Phenol Protecting Group

W Brittain, S Cobb - 2019 - chemrxiv.org
Herein, we report the development of remote regioselective electrophilic aromatic
substitution reactions enabled by the tetrafluoropyridyl (TFP) protecting group. The TFP …

遷移金属/ルイス酸協働触媒によるサイト選択的アレーンCH 官能基化

中尾佳亮 - 有機合成化学協会誌, 2021 - jstage.jst.go.jp
抄録 CH functionalization has had significant attention in organic synthesis to streamline
chemical processes of functional molecules. Efforts in the last two decades have allowed a …

イオン対相互作用による芳香族C (sp2)-H ホウ素化反応の位置選択性制御

安川直樹 - 有機合成化学協会誌, 2021 - jstage.jst.go.jp
抄録 The noncovalent interactions, such as hydrogen bonding and ion pairing interaction,
are widely recognized as the powerful tools to control enantio-and regio-selectivity in …