Acyclic and cyclic compartmental ligands: Recent results and perspectives

PA Vigato, V Peruzzo, S Tamburini - Coordination Chemistry Reviews, 2012 - Elsevier
The most relevant results published from 2006 up to 2010 are reported; they especially
regard the synthetic pathway and the structural and physico-chemical aspects of planar or …

Hydrosulfide complexes of the transition elements: diverse roles in bioinorganic, cluster, coordination, and organometallic chemistry

MD Pluth, ZJ Tonzetich - Chemical Society Reviews, 2020 - pubs.rsc.org
Sulfur-based ligands are versatile donors that play important roles in a wide array of
subdisciplines of inorganic chemistry including organometallic chemistry, bioinorganic …

Coordination chemistry of Robson-type polyamine-dithiophenolate macrocycles: Syntheses, structures and magnetic properties of dinuclear complexes of first-row …

V Lozan, C Loose, J Kortus, B Kersting - Coordination Chemistry Reviews, 2009 - Elsevier
The coordination chemistry of N-functionalized derivatives of Robson-type macrocyclic
hexamine-dithiophenolate ligands (LR) 2− is presented in this review. The ligands form …

Accessing the CpArNi(I) Synthon: Reactions with N-Heterocyclic Carbenes, TEMPO, Sulfur, and Selenium

U Chakraborty, F Urban, B Mühldorf… - …, 2016 - ACS Publications
A reactive “CpArNiI” surrogate (CpAr= C5 (C6H4-4-Et) 5) is accessible via the reduction of
the dimer [CpArNi (μ-Br)] 2 with two equivalents of KC8. A trapping reaction with TEMPO …

Thiolate coordination vs C–S bond cleavage of thiolates in dinickel (II) complexes

A Das, T Ganguly, A Majumdar - Inorganic Chemistry, 2021 - ACS Publications
A detailed study for the synthesis of dinickel (II)–thiolate and dinickel (II)–hydrosulfide
complexes and the complete characterization of the relevant intermediates involved in the C …

Chelating tris (amidate) ligands: versatile scaffolds for nickel (II)

MB Jones, BS Newell, WA Hoffert, KI Hardcastle… - Dalton …, 2010 - pubs.rsc.org
The synthesis and characterization of nickel complexes supported by a family of open-chain,
tetradentate, tris (amidate) ligands,[N (o-PhNC (O) R) 3] 3−([LR] 3− where R= iPr, tBu, and …

Interplay of Magnetic Exchange Interactions and Ni S Ni Bond Angles in Polynuclear Nickel (II) Complexes

Y Krupskaya, A Alfonsov, A Parameswaran… - …, 2010 - Wiley Online Library
The ability of bridging thiophenolate groups (RS−) to transmit magnetic exchange
interactions between paramagnetic NiII ions is examined. Specific attention is paid to …

Chemistry of metalated container molecules

B Kersting, U Lehmann - Advances in Inorganic Chemistry, 2009 - Elsevier
Publisher Summary The development of metalated container molecules has become an
attractive research goal. This is mainly because such compounds allow for interplay of …

Encapsulation of the 4-mercaptobenzoate ligand by macrocyclic metal complexes: conversion of a metallocavitand to a metalloligand

J Lach, A Jeremies, D Breite, B Abel, B Mahns… - Inorganic …, 2014 - ACS Publications
Complexation of the ambidentate ligand 4-mercaptobenzoate (4-SH-C6H4CO2H, H2mba)
by the macrocyclic complex [Ni2L (μ-Cl)] ClO4 (L2–represents a 24-membered macrocyclic …

Binuclear nickel complexes with an edge sharing bis (square-pyramidal) N 3 Ni (μ-S 2) NiN 3 core: synthesis, characterization, crystal structure and magnetic …

U Lehmann, J Lach, C Loose, T Hahn, B Kersting… - Dalton …, 2013 - pubs.rsc.org
The synthesis of the novel macrocyclic octadentate amino-thiophenolate ligand H2L2 (3, 7,
11, 19, 23, 27-hexaaza-33, 34-dithiol-15, 31-di (tert-butyl)-tricyclo [27, 3,113.17] …