Thermal and reductive decomposition of ammonium thiomolybdates

JL Brito, M Ilija, P Hernández - Thermochimica Acta, 1995 - Elsevier
Thermal decomposition and hydrogen reduction of ammonium thiomolybdates of
formulas:(NH4) 2 [MoS4](I),(NH4) 2 [Mo2 (S2) 6]· 2H2O (II) and (NH4) 2 [Mo3S (S2) 6]· 1.85 …

Thermal decomposition of ammonium molybdates

TN Kovács, D Hunyadi, ALA de Lucena… - Journal of Thermal …, 2016 - Springer
The thermal behavior of ammonium molybdates, ie,(NH 4) 6 Mo 7 O 24· 4H 2 O (1) and (NH
4) 2 MoO 4 (2), was studied in inert (N 2) and oxidizing (air) atmospheres by TG/DTA-MS …

Anderson type heteropolyoxomolybdates in catalysis:: 1.(NH4) 3 [CoMo6O24H6]· 7H2O/γ-Al2O3 as alternative of Co-Mo/γ-Al2O3 hydrotreating catalysts

CI Cabello, IL Botto, HJ Thomas - Applied Catalysis A: General, 2000 - Elsevier
A new preparation method of Co-Mo/γ-Al2O3 HDS catalyst has been developed by using
the (NH4) 3 [CoMo6O24H6]· 7H2O Anderson type heteropolyoxomolybdate supported on γ …

Decamolybdodicobaltate (III) heteropolyanion: structural, spectroscopical, thermal and hydrotreating catalytic properties

CI Cabello, FM Cabrerizo, A Alvarez… - Journal of Molecular …, 2002 - Elsevier
The ammonium decamolybdodicobaltate (III) salt:(NH4) 6 [Co2Mo10O38H4]· 7H2O (here in
Co2Mo10) has been prepared and characterized. Then, their structural, spectroscopic and …

Structural investigation of the thermal decomposition of ammonium heptamolybdate by in situ XAFS and XRD

J Wienold, RE Jentoft, T Ressler - European Journal of …, 2003 - Wiley Online Library
The decomposition of ammonium heptamolybdate (AHM,(NH4) 6Mo7O24× 4H2O) was
studied in situ by X‐ray diffraction and X‐ray absorption spectroscopy, as well as by thermal …

Raman spectroscopic evidence for the existence of 6-molybdoaluminate entities on an Mo/Al 2 O 3 oxidic precursor

L Le Bihan, P Blanchard, M Fournier… - Journal of the …, 1998 - pubs.rsc.org
A study by Raman spectroscopy of the oxomolybdate surface phase present on an
Mo/Al2O3 oxidic precursor reveals the presence of well dispersed 6-molybdoaluminate …

The Effect of Lithium on NiMo/Al2O3 Hydrotreating Catalysts Prepared from Heteropolycompounds

L Kaluža, K Jirátová, AA Spojakina, J Balabánová… - Catalysis Letters, 2024 - Springer
Recently, simultaneous hydrotreatment of various petroleum fractions and plant feedstocks
has been in demand. NiMo catalysts can be active in these processes. Therefore, supported …

(NH4) 6 [TeMo6O24]· 7H2O Anderson phase as precursor of the TeMo5O16 catalytic phase: thermal and spectroscopic studies

IL Botto, CI Cabello, HJ Thomas - Materials chemistry and physics, 1997 - Elsevier
The thermal behaviour of the (NH4) 6 [TeMo6O24]· 7H2O Anderson phase has been
analysed in N2 and H2/N2 atmospheres b differential thermal analysis and …

Molybdenum-containing systems based on natural kaolinite as catalysts for selective oxidation of aromatic sulfides

M Muñoz, MA Gallo, A Gutiérrez-Alejandre… - Applied Catalysis B …, 2017 - Elsevier
A natural kaolinite from Argentinean deposits, converted into metakaolin by thermal
treatment at 823 K and chemically modified, was used as a support for catalysts containing …

Anderson-type heteropolyoxomolybdates in catalysis: 2. EXAFS study on γ-Al2O3-supported Mo, Co and Ni sulfided phases as HDS catalysts

I Pettiti, IL Botto, CI Cabello, S Colonna… - Applied Catalysis A …, 2001 - Elsevier
The nature of the Co (or Ni) and Mo sulfided species obtained starting from γ-Al2O3-
supported Anderson heteropolyoxomolybdates (CoMo6 and NiMo6) has been analyzed by …