The chemistry of lanthanides in biology: recent discoveries, emerging principles, and technological applications

JA Cotruvo Jr - ACS central science, 2019 - ACS Publications
The essential biological role of rare earth elements lay hidden until the discovery in 2011
that lanthanides are specifically incorporated into a bacterial methanol dehydrogenase. Only …

The use of cerium compounds as antimicrobials for biomedical applications

E Barker, J Shepherd, IO Asencio - Molecules, 2022 - mdpi.com
Cerium and its derivatives have been used as remedies for wounds since the early 20th
century. Cerium nitrate has attracted most attention in the treatment of deep burns, followed …

Pseudocontact shifts in biomolecular NMR spectroscopy

T Müntener, D Joss, D Häussinger… - Chemical Reviews, 2022 - ACS Publications
Paramagnetic centers in biomolecules, such as specific metal ions that are bound to a
protein, affect the nuclei in their surrounding in various ways. One of these effects is the …

Magnetic susceptibility in paramagnetic NMR

I Bertini, C Luchinat, G Parigi - Progress in Nuclear Magnetic Resonance …, 2002 - Elsevier
1. Introduction.................................................................. 250 2. Magnetic moments,
magnetization, magnetic susceptibility................................ 250 2.1. The Curie …

NMR structure determination of protein− ligand complexes by lanthanide labeling

G Pintacuda, M John, XC Su… - Accounts of chemical …, 2007 - ACS Publications
The paramagnetism of lanthanide ions offers outstanding opportunities for fast
determinations of the three-dimensional (3D) structures of protein− ligand complexes by …

[图书][B] Handbook on metalloproteins

I Bertini, A Sigel - 2001 - taylorfrancis.com
This Handbook on Metalloproteins focuses on the available structural information of proteins
and their metal ion coordination spheres. It centers on the metal ions indispensable for life …

Coordination to lanthanide ions distorts binding site conformation in calmodulin

SC Edington, A Gonzalez… - Proceedings of the …, 2018 - National Acad Sciences
The Ca2+-sensing protein calmodulin (CaM) is a popular model of biological ion binding
since it is both experimentally tractable and essential to survival in all eukaryotic cells. CaM …

Structural characteristics of protein binding sites for calcium and lanthanide ions

E Pidcock, GR Moore - JBIC Journal of Biological Inorganic Chemistry, 2001 - Springer
Surveys of X-ray structures of Ca 2+-containing and lanthanide ion-containing proteins and
coordination complexes have been performed and structural features of the metal binding …

Structural origin of the high affinity of a chemically evolved lanthanide-binding peptide

M Nitz, M Sherawat, KJ Franz… - Angewandte …, 2004 - researchwithrutgers.com
Playing tag with terbium: New hydrophobic contacts and ligating amino acids are revealed
in the 2.0-Å resolution X-ray crystal structure of a chemically evolved 17-residue lanthanide …

Pharmacological properties of cerium compunds

MA Jakupec, P Unfried, BK Keppler - Reviews of physiology, biochemistry …, 2005 - Springer
Cerium is a member of the lanthanide series or rare earth elements which exert diverse
biological effects mainly by their resemblance to calcium. This similarity, which is particularly …