Viologens: a versatile organic molecule for energy storage applications

M Kathiresan, B Ambrose, N Angulakshmi… - Journal of Materials …, 2021 - pubs.rsc.org
Organic redox compounds are a fascinating class of active materials used in energy storage
applications. The structural diversity as well as ability to be molecularly tailored assists in …

Exploring Contemporary Advancements and Outlook in Viologen-Based Aqueous Organic Redox Flow Batteries: A Mini Review

B Ambrose, R Naresh, S Deshmukh… - Energy & …, 2023 - ACS Publications
The emerging energy needs of society encourage the use of renewable energy resources,
but the sporadic and erratic nature of renewable energy systems impedes high-efficiency …

Redox-Modulated Host–Guest Complex Realizing Stable Two-Electron Storage Viologen for Flow Battery

Y Liu, X Yuan, M Huang, Z Xiang, S Hu… - Industrial & …, 2022 - ACS Publications
Viologen is investigated as the anolyte in pH-neutral aqueous flow batteries. The full
utilization of two electrons is essential to achieve a high specific capacity, which is, however …

Supramolecular Viologen–Cyclodextrin Electrolytes for Aqueous Organic Redox Flow Batteries

A Korshunov, A Gibalova, M Gruenebaum… - ACS Applied Energy …, 2021 - ACS Publications
Along with a primary modification of redox active materials, an additional introduction of
secondary noncovalent interactions can synergistically enhance bulk properties of …

Host‐Guest Interactions Enhance the Performance of Viologen Electrolytes for Aqueous Organic Redox Flow Batteries

A Korshunov, A Gibalova, M Grünebaum… - Batteries & …, 2021 - Wiley Online Library
Host‐guest interactions are an attractive approach to design redox electrolytes, enabling to
precisely tune the key properties for redox flow batteries such as half‐cell redox potential …

Evaluation of negolyte properties of supramolecular binary complexes based on viologen-cucurbit [7] urils

B Ambrose, A Kannan, M Kathiresan - New Journal of Chemistry, 2022 - pubs.rsc.org
Viologen-based redox materials have become popular as electrolytes for aqueous organic
redox flow batteries (AORFBs) in recent years because of their reversible nature. The main …

Cucurbiturils as Effectors on the Self-Assembly of Pd (II) and Pt (II) Metallacycles

I Neira, MD García, C Peinador… - The Journal of Organic …, 2021 - ACS Publications
Four bidentate, dicationic ligands (L1 2+–L4 2+) were prepared and investigated as guests
for binding by the cucurbit [7] uril (CB [7]) host and structural components for metal (Pd and …

Observing Host–Guest Interactions at Molecular Interfaces by Monitoring the Electrochemical Current

Q Ai, L Jin, Z Gong, F Liang - ACS omega, 2020 - ACS Publications
Macrocyclic cucurbit [n] uril (CB [n]) molecules have triggered renewed interest because of
their outstanding capabilities as host molecules to selectively interact with a wide range of …

Nonlinear Dependence on Na+ Ions for the Binding Dynamics of Cucurbit[6]uril with the trans-1-Methyl-4-(4-hydroxystyryl)pyridinium Cation

H Tang, SS Thomas, L Wolf, P Natarajan… - The Journal of …, 2020 - ACS Publications
The binding dynamics of the trans-1-methyl-4-(4-hydroxystyryl) pyridinium cation (HSP+) to
cucurbit [6] uril (CB [6]) in the presence of Na+ cations were studied to establish the effect of …

6th International Conference on Cucurbiturils (ICCB2019): Athens, Ohio, USA, July 21-24th

E Masson, AR Urbach - Supramolecular Chemistry, 2020 - Taylor & Francis
ABSTRACT The most recent International Conference on Cucurbiturils (ICCB) was held at
Ohio University in Athens, Ohio. The three-day meeting included the latest advancements in …