Batteries are a promising technology in the field of electrical energy storage and have made
tremendous strides in recent few decades. In particular, lithium‐ion batteries are leading the …

This article focuses on high valence 3p and transition metal based metal organic
frameworks. In the first part we will discuss the complex solution chemistry of these metals …

1.1. Background and History Commensurate adsorption is an interesting and important
phenomenon occurring during adsorption processes, where the molecular size and shape …

This critical review focusses on a strange behaviour of crystallized solid matter: its reversible
swelling with large magnitude. This will be of interest for experts in porous solids but also for …

The synthesis on the gram scale and characterization of a series of flexible functionalized
iron terephthalate MIL-53 (Fe) type solids are reported. Chemical groups of various …

Five new flexible functionalized aluminum hydroxo terephthalates [Al (OH)(BDC-X)]· n
(guests)(BDC= 1, 4-benzene-dicarboxylate; X=-Cl, 1-Cl;-Br, 2-Br;-CH3, 3-CH 3;-NO2, 4-NO …

The vanadium-based terephthalate analogs of MIL-68 have been obtained with gallium and
indium (network composition: M (OH)(O2C− C6H4− CO2), M= Ga or In) by using a …

A continuous flow process for the synthesis of a metal–organic framework using only water
as the reaction medium and requiring only short residence times is described. This affords a …

We present a review of the structural chemistry of metal‐organic framework materials with
the MIL‐53 type structure. This family of materials is well‐known for its structural flexibility …

We describe a set of databases that bear information on geometrical and topological
properties of 1 281 254 metal coordination centers and 204 828 ligands in 593 879 crystal …