Cu/SSZ-13 and Cu/SAPO-34 catalysts for deNOx in diesel exhaust: Current status, challenges, and future perspectives

S Zhang, L Pang, Z Chen, S Ming, Y Dong, Q Liu… - Applied Catalysis A …, 2020 - Elsevier
Copper-exchanged SSZ-13 and SAPO-34 (Cu/CHA) zeolites catalysts have been
commercially utilized for selective catalytic reduction (SCR) of NO x by NH 3. Despite the …

Recent progress in the selective catalytic reduction of NOx with NH3 on Cu-SAPO-34 catalysts

M Jabłońska - Molecular Catalysis, 2022 - Elsevier
In recent years, Cu-exchanged small pore zeolites, such as Cu-SSZ-13 and Cu-SAPO-34,
have been commercially applied in diesel after-treatment systems. Several tremendous …

Unraveling the mysterious failure of Cu/SAPO-34 selective catalytic reduction catalysts

A Wang, Y Chen, ED Walter, NM Washton… - Nature …, 2019 - nature.com
Commercial Cu/SAPO-34 selective catalytic reduction (SCR) catalysts have experienced
unexpected and quite perplexing failure. Understanding the causes at an atomic level is vital …

Investigation of the robust hydrothermal stability of Cu/LTA for NH3-SCR reaction

A Wang, P Arora, D Bernin, A Kumar… - Applied Catalysis B …, 2019 - Elsevier
Recently copper ion-exchanged LTA zeolites were proved to be robust for NH 3-SCR
reaction. In this study, Cu/LTA catalysts with Si/Al= 15 and Cu/Al= 0.4 were synthesized via …

In-situ studies of oxidation/reduction of copper in Cu-CHA SCR catalysts: comparison of fresh and SO2-poisoned catalysts

SL Bergman, S Dahlin, VV Mesilov, Y Xiao… - Applied Catalysis B …, 2020 - Elsevier
SO 2-poisoning results in deactivation of Cu-CHA SCR under standard SCR conditions;
however regeneration at 700° C completely restores the SCR performance. To understand …

Deactivation mechanism of Cu active sites in Cu/SSZ-13—Phosphorus poisoning and the effect of hydrothermal aging

A Wang, K Xie, D Bernin, A Kumar… - Applied Catalysis B …, 2020 - Elsevier
Non-poisoned and P-poisoned Cu/SSZ-13 catalysts with different types of Cu sites, ie,[Cu
(OH)]+ and Cu 2+, were investigated for NH 3-SCR. Phosphorus was found to interact more …

Efficient one-pot synthesis of Cu-SAPO-34 catalysts for NH3-SCR of NOx

J He, D Mao, J Hou, C Zhong, C Yin, Z Zhao, RT Yang - Fuel, 2023 - Elsevier
Cu-SAPO-34 shows high catalytic performance in ammonia selective catalytic reduction (NH
3-SCR) of nitrogen oxides (NO x). Complex synthesis methods and environmental pollution …

Critical roles of Cu (OH) 2 in low-temperature moisture-induced degradation of Cu-SAPO-34 SCR catalyst: Correlating reversible and irreversible deactivation

Y Ma, X Wu, L Liu, L Cao, R Ran, Z Si, F Gao… - Applied Catalysis B …, 2020 - Elsevier
Cu-SAPO-34 selective catalytic reduction (SCR) catalyst deactivates upon exposure to water
vapor at temperatures lower than 100° C, which deteriorates its application prospects. The …

Fe-Exchanged Small-Pore Zeolites as Ammonia Selective Catalytic Reduction (NH3-SCR) Catalysts

F Gao - Catalysts, 2020 - mdpi.com
Cu-exchanged small-pore zeolites have been extensively studied in the past decade as
state-of-the-art selective catalytic reduction (SCR) catalysts for diesel engine exhaust NOx …

Comprehensive effect of tuning Cu/SAPO-34 crystals using PEG on the enhanced hydrothermal stability for NH 3-SCR

Q Lin, S Liu, S Xu, S Xu, M Pei, P Yao, H Xu… - Catalysis Science & …, 2021 - pubs.rsc.org
The high-efficiency NH3-assisted selective catalytic reduction (NH3-SCR) technology
continues to attract wide attention in diminishing harmful nitrogen oxides (NOx) from diesel …