Rare earth starting materials and methodologies for synthetic chemistry
F Ortu - Chemical Reviews, 2022 - ACS Publications
The number of rare earth (RE) starting materials used in synthesis is staggering, ranging
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …
Anhydrous scandium, yttrium, lanthanide and actinide halide complexes with neutral oxygen and nitrogen donor ligands
S Mishra - Coordination Chemistry Reviews, 2008 - Elsevier
Studies on lanthanide and actinide halide complexes with neutral O-and/or N-donor ligands
have intensified in recent years due to their implications in homogeneous catalysis …
have intensified in recent years due to their implications in homogeneous catalysis …
Crown-Ether Coordination Compounds of Europium and 24-Crown-8
MA Bonnin, S Leicht, C Feldmann - Inorganic Chemistry, 2025 - ACS Publications
Crown-ether coordination compounds of europium (II/III) and the crown ether (C2H4O) 8 (24-
crown-8, 24c8) are prepared, aiming at novel compounds, structures, and coordination …
crown-8, 24c8) are prepared, aiming at novel compounds, structures, and coordination …
Asymmetric compartmental macrocyclic ligands and related mononuclear and hetero-dinuclear complexes with d-and/or f-metal ions
N Brianese, U Casellato, S Tamburini, P Tomasin… - Inorganica chimica …, 1999 - Elsevier
[1+ 1] Asymmetric compartmental macrocycles H2L (H2LA–H2LG), containing one N2O2,
N3O2 or N2O2O2 Schiff base and one adjacent O2O3, O2O4 or O2O5 'crown …
N3O2 or N2O2O2 Schiff base and one adjacent O2O3, O2O4 or O2O5 'crown …
Synthesis, X-ray structure, and solution NMR studies of Ln (III) complexes with a macrocyclic asymmetric compartmental Schiff base. Preference of the Ln (III) ions for a …
U Casellato, S Tamburini, P Tomasin… - Inorganic …, 1999 - ACS Publications
The compartmental ligand H2LA, containing an N3O2 Schiff base and an O2O3 crown like
coordination site, has been prepared by reaction of 3, 3 '-(3-oxapentane-1, 5-diyldioxy) bis …
coordination site, has been prepared by reaction of 3, 3 '-(3-oxapentane-1, 5-diyldioxy) bis …
Halide abstraction from Pr (III) chloride by Sn (IV): formation and crystal structures of [Pr (MeCN) 9][SnCl5 (THF)] 2.5 [SnCl5 (MeCN)] 0.5,[Pr (MeCN) 9][SnCl5 (MeCN)] …
GR Willey, DR Aris, W Errington - Inorganica Chimica Acta, 2001 - Elsevier
Treatment of PrCl3 with SnCl4 and dibenzo-24-crown-8 in MeCN/THF (60/40) afforded [Pr
(MeCN) 9][SnCl5 (THF)] 2.5 [SnCl5 (MeCN)] 0.5 (I) as the only isolated product. From the …
(MeCN) 9][SnCl5 (THF)] 2.5 [SnCl5 (MeCN)] 0.5 (I) as the only isolated product. From the …
Europium(II) Complexes With Benzo‐18‐Crown‐6
P Starynowicz, K Bukietyńska, S Gołąb… - European Journal of …, 2002 - Wiley Online Library
Two compounds of EuII with benzo‐18‐crown‐6, triaqua (benzo‐18‐crown‐6) europium (ii)
diperchlorate (1) and triaqua (benzo‐18‐crown‐6) europium (ii) perchlorate hydrate benzo …
diperchlorate (1) and triaqua (benzo‐18‐crown‐6) europium (ii) perchlorate hydrate benzo …
Halide-abstraction reactions of tin (IV) and lanthanide (III) chlorides in tetrahydrofuran: crystal and molecular structures of [LnCl 2 (thf) 5][SnCl 5 (thf)] where Ln= Ce, Gd …
GR Willey, TJ Woodman, DJ Carpenter… - Journal of the Chemical …, 1997 - pubs.rsc.org
It has been established that halide abstraction from several lanthanide (III) chlorides can be
effected by tin tetrachloride. Direct treatment (1∶ 1) of LnCl 3 where Ln= Ce, Gd or Yb with …
effected by tin tetrachloride. Direct treatment (1∶ 1) of LnCl 3 where Ln= Ce, Gd or Yb with …
Crown ether complexation of PrCl2+: Synthesis and structural characterisation of [PrCl2 (dibenzo-18-crown-6)(H2O)][SbCl6]· 0.5 MeOH· 0.5 MeCN
GR Willey, PR Meehan, PA Salter, MGB Drew - Polyhedron, 1996 - Elsevier
Treatment of PrCl3 (MeCN) 3.5 with antimony (V) chloride in the presence of dibenzo-18-
crown-6 provided yellow needle crystals of [PrCl2 (dibenzo-18-crown-6)(H2)][SbCl6]· 0.5 …
crown-6 provided yellow needle crystals of [PrCl2 (dibenzo-18-crown-6)(H2)][SbCl6]· 0.5 …
Nitrile‐Supported Coordination Polymers of Cerium (III) Bromide
KV Vasudevan, WL Boncher, NA Smith… - European Journal of …, 2014 - Wiley Online Library
A series of nitrile‐supported coordination polymers of cerium bromide (CeBr3) are reported,
including adducts of trimethylacetonitrile, benzonitrile, and glutaronitrile. The identities of the …
including adducts of trimethylacetonitrile, benzonitrile, and glutaronitrile. The identities of the …