Non-toxic cyanide sources and cyanating agents

AM Nauth, T Opatz - Organic & Biomolecular Chemistry, 2019 - pubs.rsc.org
The present review gives an overview over non-toxic cyanation agents and cyanide sources
used in the synthesis of structurally diverse products containing the nitrile function …

Green synthesis of copper nanoparticles using Plantago asiatica leaf extract and their application for the cyanation of aldehydes using K4Fe (CN) 6

M Nasrollahzadeh, SS Momeni, SM Sajadi - Journal of colloid and interface …, 2017 - Elsevier
Abstract Copper nanoparticles (Cu NPs) were synthesized via a green method by using of
Plantago asiatica leaf extract as natural solvent and reaction biomedia under …

Insights into the chemistry and therapeutic potential of acrylonitrile derivatives

O Unsal Tan, M Zengin - Archiv der Pharmazie, 2022 - Wiley Online Library
Acrylonitrile is a fascinating scaffold widely found in many natural products, drugs, and drug
candidates with various biological activities. Several drug molecules such as entacapone …

Green synthesis of Pd nanoparticles mediated by Euphorbia thymifolia L. leaf extract: catalytic activity for cyanation of aryl iodides under ligand-free conditions

M Nasrollahzadeh, SM Sajadi - Journal of colloid and interface science, 2016 - Elsevier
Pd nanoparticles (NPs) were synthesized by using aqueous extract of leaves of Euphorbia
thymifolia L., a non-toxic ecofriendly material. The catalytic activity of the Pd NPs was …

Cyanation of aryl halides and Suzuki-Miyaura coupling reaction using palladium nanoparticles anchored on developed biodegradable microbeads

T Baran, M Nasrollahzadeh - International journal of biological …, 2020 - Elsevier
This work reports i) green synthesis of palladium nanoparticles (Pd NPs) on the developed
biodegradable microbeads as stabilizers, featuring chitosan, agarose and beta-cyclodextrin …

Rhodium-Catalyzed Cyanation of C(sp2)–H Bond of Alkenes

M Chaitanya, P Anbarasan - Organic letters, 2015 - ACS Publications
Efficient and selective rhodium-catalyzed cyanation of chelation-assisted C–H bonds of
alkenes has been accomplished using environmentally benign N-cyano-N-phenyl-p …

A vinylic Rosenmund–von Braun reaction: practical synthesis of acrylonitriles

A Pradal, G Evano - Chemical communications, 2014 - pubs.rsc.org
An efficient system based on acetone cyanohydrin and catalytic amounts of copper (I) iodide
and 1, 10-phenanthroline is reported for the cyanation of alkenyl iodides. A wide range of …

Palladium‐Catalyzed One‐Pot Four‐Component Synthesis of β‐Cyano‐α, β‐unsaturated Ketones Using Calcium Carbide as an Acetylene Source and Potassium …

H Lu, Z Li - Advanced Synthesis & Catalysis, 2019 - Wiley Online Library
Palladium‐catalyzed one‐pot four‐component synthesis of β‐cyano‐α, β‐unsaturated
ketones by the reactions of aryl halides, calcium carbide, potassium hexacyanoferrate (II) …

Mild and Copper‐Free Stereoselective Cyanation of gem‐Difluoroalkenes by Using Benzyl Nitrile as a Cyanating Reagent

J Zhang, C Xu, W Wu, S Cao - Chemistry–A European Journal, 2016 - Wiley Online Library
A novel copper‐free highly stereoselective cyanation of gem‐difluoroalkenes by using
benzyl nitrile as a cyanating reagent with the assistance of tBuOLi under air atmosphere at …

Pd/CuO nanoparticles as a highly effective catalyst for the cyanation of aryl halides under ligand-free conditions

M Nasrollahzadeh - Tetrahedron Letters, 2016 - Elsevier
Copper oxide supported palladium nanoparticles have been used as a separable catalyst
for the cyanation of a range of aryl iodides and bromides under ligand-free conditions. The …