Advances in computational studies of the liquid–liquid transition in water and water-like models

JC Palmer, PH Poole, F Sciortino… - Chemical …, 2018 - ACS Publications
There has been uninterrupted interest in supercooled water ever since the pioneering
experiments of Speedy and Angell revealed sharp increases in this substance's response …

Advances in the study of supercooled water

P Gallo, J Bachler, LE Bove, R Böhmer… - The European Physical …, 2021 - Springer
In this review, we report recent progress in the field of supercooled water. Due to its
uniqueness, water presents numerous anomalies with respect to most simple liquids …

The anomalies and criticality of liquid water

R Shi, H Tanaka - Proceedings of the National Academy of …, 2020 - National Acad Sciences
The origin of water's anomalies has been a matter of long-standing debate. A two-state
model, dating back to Röntgen, relies on the dynamical coexistence of two types of local …

Thermodynamics of fluid polyamorphism

MA Anisimov, M Duška, F Caupin, LE Amrhein… - Physical Review X, 2018 - APS
Fluid polyamorphism is the existence of different condensed amorphous states in a single-
component fluid. It is either found or predicted, usually at extreme conditions, for a broad …

Enhancement and maximum in the isobaric specific-heat capacity measurements of deeply supercooled water using ultrafast calorimetry

H Pathak, A Späh, N Esmaeildoost… - Proceedings of the …, 2021 - National Acad Sciences
Knowledge of the temperature dependence of the isobaric specific heat (Cp) upon deep
supercooling can give insights regarding the anomalous properties of water. If a maximum in …

The physics of empty liquids: From patchy particles to water

J Russo, F Leoni, F Martelli… - Reports on Progress in …, 2022 - iopscience.iop.org
Empty liquids represent a wide class of materials whose constituents arrange in a random
network through reversible bonds. Many key insights on the physical properties of empty …

Thermodynamics of supercooled and stretched water: Unifying two-structure description and liquid-vapor spinodal

F Caupin, MA Anisimov - The Journal of Chemical Physics, 2019 - pubs.aip.org
We have applied a two-structure approach to the description of the thermodynamic
properties of supercooled and stretched water, metastable toward vapor, ice, or both, by …

Perspective: Crossing the Widom line in no man's land: Experiments, simulations, and the location of the liquid-liquid critical point in supercooled water

NJ Hestand, JL Skinner - The Journal of Chemical Physics, 2018 - pubs.aip.org
The origin of liquid water's anomalous behavior continues to be a subject of interest and
debate. One possible explanation is the liquid-liquid critical point hypothesis, which …

Viscosity and self-diffusion of supercooled and stretched water from molecular dynamics simulations

P Montero de Hijes, E Sanz, L Joly… - The Journal of …, 2018 - pubs.aip.org
Among the numerous anomalies of water, the acceleration of dynamics under pressure is
particularly puzzling. Whereas the diffusivity anomaly observed in experiments has been …

Water-like anomalies as a function of tetrahedrality

J Russo, K Akahane, H Tanaka - Proceedings of the …, 2018 - National Acad Sciences
Tetrahedral interactions describe the behavior of the most abundant and technologically
important materials on Earth, such as water, silicon, carbon, germanium, and countless …