Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

This microreview describes the structures and properties of a number of bimetallic
complexes designed as both structural and functional mimics of the active sites of some …

Purple acid phosphatases (PAPs) are a group of metallohydrolases that contain a dinuclear
FeIIIMII center (MII= Fe, Mn, Zn) in the active site and are able to catalyze the hydrolysis of a …

Two dinuclear copper complexes with and without ammonium moieties were synthesized.
The complexes exhibited selective binding affinity to pyrophosphate in aqueous solution …

Flavodiiron nitric oxide reductases (FNORs), a common enzyme family found in various
types of pathogenic bacteria, are capable of reducing nitric oxide (NO) to nitrous oxide …

Very few inorganic antineoplastic drugs have entered the clinic in the last decades, mainly
because of toxicity issues. Because copper is an essential trace element of ubiquitous …

A new semi-empirical magnetostructural correlation for exchange coupled dinuclear
asymmetrically phenoxo-, alkoxo-, and hydroxo-bridged iron (III) complexes has been …

Species 1− 6 are [MIII (L) 2] ClO4 complexes formed with the PhO-− CH N− CH2− Py
imines,(LI)-and (L tBuI)-, and PhO-− CH2− NH− CH2− Py amines,(LA)-and (L tBuA)-, in …

A novel heterobinuclear mixed valence complex [Fe III Cu II (BPBPMP)(OAc) 2] ClO 4, 1,
with the unsymmetrical N 5 O 2 donor ligand 2-bis [{(2-pyridylmethyl) aminomethyl}-6-{(2 …

The design and development of suitable biomimetic catalytic systems capable of mimicking
the functional properties of enzymes continues to be a challenge for bioinorganic chemists …