Direct C–H bond functionalization catalyzed by non-precious transition metals is an
attractive strategy in synthetic chemistry. Compared with the precious metals rhodium …

Transition-metal-catalyzed carbene transfer reactions, involving diazo compounds and their
precursors, are powerful tools for creating new C–C bonds. Depending on the involved …

Recognizing Nature's unique ability to perform challenging oxygenation reactions with
exquisite selectivity parameters at iron-dependent oxygenases, chemists have long sought …

Lewis acidic boranes have been shown to be effective metal-free catalysts for highly
selective reactions of donor-acceptor diazo compounds to a range of substrates. The …

Carbene transfer reactions hold a pivotal role in organic synthesis, allowing the prompt
construction of complex molecules from accessible reagents. Iron complexes emerged as …

Herein, we have developed a novel B (C 6 F 5) 3-catalysed S–H bond insertion of
thiophenols and thiols with α-aryl-α-diazoesters under mild conditions, furnishing various …

The direct CH functionalization reaction is one of the most efficient strategies by which to
introduce new functional groups into small organic molecules. Over time, iron complexes …

Herein, we reported the first copper-catalyzed highly efficient C (sp2)–H functionalization of
unprotected naphthols and phenols with α-aryl-α-diazoesters. In this transformation, CuCl2 …

A three‐component reaction of N, N‐disubstituted aniline, α‐diazo ester, and an allylic
electrophile has been realized by [Rh (II)] 2/Xantphos catalysis, providing a direct access to …

Herein, we disclose a highly stereoselective Rh (II)-catalyzed 1, 4-acyl rearrangement of
selenium esters and α-diazo carbonyl compounds, which provides an efficient method for …