The nature and reactivity of ferryl heme in compounds I and II

PCE Moody, EL Raven - Accounts of chemical research, 2018 - ACS Publications
Conspectus Aerobic organisms have evolved to activate oxygen from the atmosphere, which
allows them to catalyze the oxidation of different kinds of substrates. This activation of …

Metals in protein structures: a review of their principal features

MM Harding, MW Nowicki… - Crystallography …, 2010 - Taylor & Francis
Metals are present in more than one-third of all proteins as they occur in nature, and are
usually important in biological function or maintenance of the structure. Some are present as …

Neutron cryo-crystallography captures the protonation state of ferryl heme in a peroxidase

CM Casadei, A Gumiero, CL Metcalfe, EJ Murphy… - Science, 2014 - science.org
Heme enzymes activate oxygen through formation of transient iron-oxo (ferryl) intermediates
of the heme iron. A long-standing question has been the nature of the iron-oxygen bond …

Neutron protein crystallography: A complementary tool for locating hydrogens in proteins

WB O'Dell, AM Bodenheimer, F Meilleur - Archives of Biochemistry and …, 2016 - Elsevier
Neutron protein crystallography is a powerful tool for investigating protein chemistry
because it directly locates hydrogen atom positions in a protein structure. The visibility of …

Biomolecular deuteration for neutron structural biology and dynamics

M Haertlein, M Moulin, JM Devos, V Laux… - Methods in …, 2016 - Elsevier
Neutron scattering studies provide important information in structural biology that is not
accessible using other approaches. The uniqueness of the technique, and its …

Determination of the electronic and structural configuration of coordination compounds by synchrotron-radiation techniques

C Garino, E Borfecchia, R Gobetto… - Coordination Chemistry …, 2014 - Elsevier
In this review we provide an overview of the potential of synchrotron radiation techniques to
understand the structural and electronic properties of coordination compounds. Besides the …

Neutron scattering in the biological sciences: progress and prospects

R Ashkar, H Bilheux, H Bordallo, R Briber… - … Section D: Structural …, 2018 - journals.iucr.org
The scattering of neutrons can be used to provide information on the structure and dynamics
of biological systems on multiple length and time scales. Pursuant to a National Science …

[HTML][HTML] A suite-level review of the neutron single-crystal diffraction instruments at Oak Ridge National Laboratory

L Coates, HB Cao, BC Chakoumakos… - Review of Scientific …, 2018 - pubs.aip.org
The nascent suite of single-crystal neutron diffractometers at the Oak Ridge National
Laboratory has no equal at any other neutron scattering facility worldwide and offers the …

Perdeuterated GbpA enables neutron scattering experiments of a lytic polysaccharide monooxygenase

HV Sørensen, M Montserrat-Canals, JSM Loose… - ACS …, 2023 - ACS Publications
Lytic polysaccharide monooxygenases (LPMOs) are surface-active redox enzymes that
catalyze the degradation of recalcitrant polysaccharides, making them important tools for …

Neutron macromolecular crystallography with LADI-III

MP Blakeley, SCM Teixeira… - … Section D: Biological …, 2010 - journals.iucr.org
At the Institut Laue–Langevin, a new neutron Laue diffractometer LADI-III has been fully
operational since March 2007. LADI-III is dedicated to neutron macromolecular …