Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development

C Sambiagio, SP Marsden, AJ Blacker… - Chemical Society …, 2014 - pubs.rsc.org
Cu-catalysed arylation reactions devoted to the formation of C–C and C–heteroatom bonds
(Ullmann-type couplings) have acquired great importance in the last decade. This review …

Safe, Scalable, Inexpensive, and Mild Nickel‐Catalyzed Migita‐Like C− S Cross‐Couplings in Recyclable Water

TY Yu, H Pang, Y Cao, F Gallou… - Angewandte Chemie …, 2021 - Wiley Online Library
A new approach to C− S couplings is reported that relies on nickel catalysis under mild
conditions, enabled by micellar catalysis in recyclable water as the reaction medium. The …

Synthesis of organochalcogen compounds using non‐conventional reaction media

G Perin, D Alves, RG Jacob, AM Barcellos… - …, 2016 - Wiley Online Library
Organochalcogen compounds (containing S, Se and Te) are interesting either for use as an
intermediate in the synthesis of complex molecules or for the exploitation of their biological …

Generation, regeneration, and recovery of Cu catalytic system by changing the polarity of electrodes

KS Rodygin, DE Samoylenko, MM Seitkalieva… - Green …, 2022 - pubs.rsc.org
Considering a complete life cycle of metal catalysts, metals are usually mined from ores as
salts (MX′ n), industrially processed to the bulk metal (M) and then converted into the salts …

Formation of C–C, C–S and C–N bonds catalysed by supported copper nanoparticles

AY Mitrofanov, AV Murashkina… - Catalysis Science & …, 2017 - pubs.rsc.org
Transition-metal catalysed cross-coupling reactions are still dominated by palladium
chemistry. Within the recent past, copper has gained ground against palladium by virtue of …

DMSO/iodine-catalyzed oxidative C–Se/C–S bond formation: a regioselective synthesis of unsymmetrical chalcogenides with nitrogen-or oxygen-containing arenes

S Saba, J Rafique, AL Braga - Catalysis Science & Technology, 2016 - pubs.rsc.org
A convenient metal-free and solvent-free iodine-catalyzed regioselective greener protocol to
access different types of unsymmetrical chalcogenides with nitrogen-or oxygen-containing …

One-pot thioetherification of aryl halides with thiourea and benzyl bromide in water catalyzed by Cu-grafted furfural imine-functionalized mesoporous SBA-15

J Mondal, A Modak, A Dutta, S Basu, SN Jha… - Chemical …, 2012 - pubs.rsc.org
Surface functionalization of SBA-15 followed by its reaction with Cu (OAc) 2 has been
carried out to develop a new Cu-grafted functionalized mesoporous material, which …

Sulfides synthesis: nanocatalysts in C–S cross-coupling reactions

L Shiri, A Ghorbani-Choghamarani… - Australian Journal of …, 2016 - CSIRO Publishing
The C–S cross-coupling reaction of aryl halides with thiols or sulfur sources is a key and
valuable synthetic transformation in chemistry and medicine as well as in biology, and the …

Highly dispersed silica-supported nanocopper as an efficient heterogeneous catalyst: application in the synthesis of 1, 2, 3-triazoles and thioethers

P Veerakumar, M Velayudham, KL Lu… - Catalysis Science & …, 2011 - pubs.rsc.org
In this paper, we report the synthesis of amine modified SiNPs (silica nanoparticles) by a sol–
gel method and the role of synthesized SiO2 as a solid support for the nanocatalyst CuNPs …