Cyanide‐bridged molecular squares offer a unique opportunity for study, as they represent a
model of the simplest unit of Prussian blue and allow access to a wide range of physical …

Chemistry of Schiff base (SB) ligands began in 1864 due to the discovery made by Hugo
Schiff (Schiff, H., Justus Liebigs Ann. der Chemie 1864, 131 (1), 118–119). However, there is …

We report here the spectroscopic properties of four very closely related mixed-valence
cyanide-bridged bimetallic complexes, trans-[Ru (T)(bpy)(μ-NC) Ru (L) 4 (CN)] 3+(T= tris (1 …

The unique enantiopure {[Λ-CoII ((R)-mpm) 2] 3 [WV (CN) 8] 2}· 9H2O [(R)-1] and {[Δ-CoII
((S)-mpm) 2] 3 [WV (CN) 8] 2}· 9H2O [(S)-1], where mpm= α-methylpyridinemethanol …

Herein we report the first hybrid magnetic material resulting from the intercalation of a
cyanide-based molecular magnet into a solid-state layered host. More specifically, the use of …

Shape-persistent ligands with triptycene groups are promising candidates for the
development of porous metal–organic frameworks with functional surface area. In this work …

The self-assembly of [CuII (dien)(H2O) 2] 2+ and [WV (CN) 8] 3− in aqueous solution leads
to the formation (H3O){[CuII (dien)] 4 [WV (CN) 8]}[WV (CN) 8] 2· 6.5 H2O (1). The crystal …

We have detected the existence of different geometrical isomers of high-spin Ni9W6 clusters
with symmetrical bidentate blocking ligands, and have proposed the classifications of the …

Представлены экспериментальные и теоретические результаты по исследованию
спиновых кроссоверов в магнитоупорядоченных материалах. Рассмотрено влияние …

New dodecanuclear bimetallic Ni8M4 clusters were obtained in the reaction between
octacyanometallates (IV), nickel (II) cations and diimine ligands.{[Ni (LL)(H2O)] 2 [Ni …