The host–guest composites of Hofmann‐type iron (II) spin‐transition (ST) porous
coordination polymers incorporating guest molecules show guest‐dependent ST behavior in …

Abstract 2, 2′: 6′, 2 ″-Terpyridine (tpy)-based transition metal complexes have continued
to receive attention due to their outstanding features and promising industrial and …

A systematic study of the performance of several density functional methodologies to study
spin-crossover (SCO) on first row transition metal complexes is reported. All functionals have …

The synthesis and characterization of a new Co (II) spin‐crossover (SCO) complex based on
4′‐(4‐carboxyphenyl)− 2, 2′: 6′, 2 ″‐terpyridine ligand are reported. This complex can …

Cooperative spin crossover transitions with thermal hysteresis loops are rarely observed in
cobalt (II) complexes. Herein, two new mononuclear cobalt (II) complexes with hysteretic …

The development of molecule-based switchable materials remains an important challenge
in the field of molecular science. Achievement of a structural phase transition induced by …

A novel hydrogen-bonded metal-organic framework (H-MOF)[Co (HL) 2](DMF) 1.2 (H2O) 2.4
(1· solv), in which L= 2, 2′: 6′, 2′′-terpyridine-5, 5'-diyl biscarboxylate, was prepared …

We report a series of meltable FeII complexes, which, depending on the length of aliphatic
chains, display abrupt forward low‐spin to high‐spin transition or unprecedented melting …

Two mononuclear nickel (II) complexes of the formula [Ni (terpyCOOH) 2](ClO4) 2∙ 4H2O (1)
and [Ni (terpyepy) 2](ClO4) 2 MeOH (2)[terpyCOOH= 4′-carboxyl-2, 2′: 6′, 2 …

Spin energetics is one of the biggest challenges associated with energy calculations for
electronic structure methods. The energy differences of the spin states in spin-crossover …