Cyclic polymers: Controlled synthesis, properties and perspectives

RT Gao, L Xu, SY Li, N Liu, Z Chen… - Chemistry–A European …, 2023 - Wiley Online Library
Recently, cyclic polymers have attracted increasing interest due to their unique topologies,
properties, and functions compared to the linear analogues. This mini‐review focuses on the …

Polyphosphonate covalent organic frameworks

K Xu, R Oestreich, T Haj Hassani Sohi… - Nature …, 2024 - nature.com
Herein, we report polyphosphonate covalent organic frameworks (COFs) constructed via
POP linkages. The materials are synthesized via a single-step condensation reaction of the …

Strategies towards orthopaedic tissue engineered graft generation: current scenario and application

SP Mallick, Z Beyene, DK Suman, A Madhual… - Biotechnology and …, 2019 - Springer
Even though degradation and damage to bone and cartilage tissue can be resolved
naturally, but there is a great challenge to regenerate functional tissue due to multiple …

An investigation of polyphosphinoboranes as flame-retardant materials

AW Knights, MA Nascimento, I Manners - Polymer, 2022 - Elsevier
Phosphorus-containing polymers are of considerable interest as flame-retardants additives.
We report investigations into the flame-retardant properties of a series of …

Low‐Temperature Thermal Formation of the Cyclic Methylphosphonic Acid Trimer [c‐(CH3PO2)3]

C Zhang, AM Turner, J Wang, JH Marks… - …, 2023 - Wiley Online Library
We report the formation of the cyclic methylphosphonic acid trimer [c‐(CH3PO2) 3] through
condensation reactions during thermal processing of low‐temperature methylphosphonic …

Synthesis and Ligand Properties of Chelating Bis(N-heterocyclic carbene)-Stabilized Bis(phosphinidenes)

JE Siewert, BM Puerta Lombardi, N Jannsen… - Inorganic …, 2023 - ACS Publications
NHC–phosphinidene (NHCP) adducts are an emerging class of ligands with proven binding
ability for main group and transition metal elements. They possess electron-rich P atoms …

High Molar Mass Poly(alkylphosphinoboranes) via Iron-Catalyzed Dehydropolymerization

DA Resendiz-Lara, VT Annibale, AW Knights… - …, 2020 - ACS Publications
High molar mass polyphosphinoboranes substituted with an alkyl group at phosphorus
[RPH–BH2] n (R= t Bu, 1-Ad, i Pr, Cy, n Hex, and Me) have been successfully prepared via …

Coordination-induced polymerization of P═C bonds leads to regular (P─C)n polycarbophosphanes

Y Mei, JJ Gamboa-Carballo, Y Bao, N Wu… - Science …, 2021 - science.org
The replacement of carbon in (C─ C) n chains of polyolefins by phosphorus leads to
polycarbophosphanes (P─ C) n, which may possess unique chemical and physical …

Ian Manners (1961-2023): Learning to Fly.

E Leitao, H MacKenzie - Angewandte Chemie (International ed. in …, 2024 - europepmc.org
Ian Manners, an internationally renowned main-group and materials scientist, passed away
on December 3, 2023. He will be remembered as a brilliant researcher, an avid …

Transition‐Metal‐Free Dehydropolymerization of Phosphine–Boranes at Ambient Temperature

MA Wiebe, S Kundu, EA LaPierre… - … A European Journal, 2023 - Wiley Online Library
Stoichiometric reaction of phosphine–borane adducts RR'PH⋅ BH3 (R= Ph, R'= H, Ph, Et,
and R= R'= tBu) with the strong acid HNTf2 (Tf= SO2CF3) leads to H2 elimination and the …