[HTML][HTML] Acetylene in organic synthesis: Recent progress and new uses

VV Voronin, MS Ledovskaya, AS Bogachenkov… - Molecules, 2018 - mdpi.com
Recent progress in the leading synthetic applications of acetylene is discussed from the
prospect of rapid development and novel opportunities. A diversity of reactions involving the …

Advances and mechanistic insights in the catalytic semi-hydrogenation of acetylene over non-metallic catalysts

F Zhang, Q Zhang, Y Chen, L Xu, Z Li, Q Wang… - Applied Catalysis A …, 2023 - Elsevier
Acetylene semi-hydrogenation reaction is a critical transformation process for removing
trace levels of acetylene from industrial ethylene streams. Noble metal catalysts are …

Critical role of solvent-modulated hydrogen-binding strength in the catalytic hydrogenation of benzaldehyde on palladium

G Cheng, A Jentys, OY Gutiérrez, Y Liu, YH Chin… - Nature Catalysis, 2021 - nature.com
Solvents not only disperse reactants to enhance mass transport in catalytic reactions but
also alter the reaction kinetically. Here, we show that the rate of benzaldehyde …

Defect-rich activated carbons as active and stable metal-free catalyst for acetylene hydrochlorination

Y Qiu, S Ali, G Lan, H Tong, J Fan, H Liu, B Li, W Han… - Carbon, 2019 - Elsevier
A defect-rich activated carbon featured superior catalytic performance and stability for
acetylene hydrochlorination as metal-free catalysts. Raman and density functional theory …

[HTML][HTML] Filled carbon-nanotube heterostructures: from synthesis to application

Y Teng, J Li, J Yao, L Kang, Q Li - Microstructures, 2023 - oaepublish.com
Carbon nanotubes (CNTs) have a one-dimensional (1D) hollow tubular structure formed by
graphene curling with remarkable electronic, optical, mechanical, and thermal properties …

Effect of doping Cr on NH3 adsorption and NO oxidation over the FexOy/AC surface: A DFT-D study

C Xie, B Zhu, Y Sun, W Song, M Xu - Journal of Hazardous Materials, 2021 - Elsevier
Activated carbon supported iron-based catalysts (Fe x O y/AC) show good deNO x efficiency
at low temperature. The doping of chromium (Cr) greatly improves the catalyst activity …

Ambient-condition acetylene hydrogenation to ethylene over WS2-confined atomic Pd sites

W Zhang, K Uwakwe, J Hu, Y Wei, J Zhu… - Nature …, 2024 - nature.com
Ambient-condition acetylene hydrogenation to ethylene (AC-AHE) is a promising process for
ethylene production with minimal additional energy input, yet remains a great challenge due …

Adsorption mechanism of NH 3, NO, and O 2 molecules over the Fe x O y/AC catalyst surface: a DFT-D3 study

C Xie, Y Sun, B Zhu, W Song, M Xu - New Journal of Chemistry, 2021 - pubs.rsc.org
Activated carbon-supported iron-based catalysts (FexOy/AC) show excellent deNOx
efficiency. However, the specific adsorption mechanism of NH3, NO, and O2 molecules on …

The role of carbon nanotubes in the reactions of heterogeneous catalysis

P De Luca, C Siciliano, JB Nagy, A Macario - … Engineering Research and …, 2023 - Elsevier
In this review the most significant results reported in the literature concerning the use of
carbon nanotubes in heterogeneous catalytic reactions are reported. Carbon nanotubes are …

Metal-free catalysts for hydrogenation

Q Dai, L Dai - Nature Chemistry, 2024 - nature.com
Ethylene feedstocks must be ultrapure for plastics production, but metal-based catalysts
used for acetylene removal are limited by cost, scarcity and durability. Now, electrochemical …