Molecular enhancement of heterogeneous CO2 reduction

DH Nam, P De Luna, A Rosas-Hernández… - Nature materials, 2020 - nature.com
The electrocatalytic carbon dioxide reduction reaction (CO2RR) addresses the need for
storage of renewable energy in valuable carbon-based fuels and feedstocks, yet challenges …

Molecular and heterogeneous water oxidation catalysts: recent progress and joint perspectives

J Li, CA Triana, W Wan, DPA Saseendran… - Chemical Society …, 2021 - pubs.rsc.org
The development of reliable water oxidation catalysts (WOCs) is essential for implementing
artificial photosynthesis on a large technological scale. WOC research has evolved into two …

Metal–organic frameworks embedded in a liposome facilitate overall photocatalytic water splitting

H Hu, Z Wang, L Cao, L Zeng, C Zhang, W Lin… - Nature Chemistry, 2021 - nature.com
Metal–organic frameworks (MOFs) have been studied extensively in the hydrogen evolution
reaction (HER) and the water oxidation reaction (WOR) with sacrificial reagents, but overall …

A supramolecular artificial light‐harvesting system with two‐step sequential energy transfer for photochemical catalysis

M Hao, G Sun, M Zuo, Z Xu, Y Chen, XY Hu… - Angewandte …, 2020 - Wiley Online Library
An artificial light‐harvesting system with sequential energy‐transfer process was fabricated
based on a supramolecular strategy. Self‐assembled from the host–guest complex formed …

Molecular catalysts for water oxidation

JD Blakemore, RH Crabtree, GW Brudvig - Chemical Reviews, 2015 - ACS Publications
The development of technologies for the production of chemical fuels or useful compounds
with renewable energy (eg, sunlight) and inexpensive feedstocks relies on an abundant …

Molecular chromophore–catalyst assemblies for solar fuel applications

DL Ashford, MK Gish, AK Vannucci… - Chemical …, 2015 - ACS Publications
As the world's population increases, the US Department of Energy has estimated that energy
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …

Polyoxometalate water oxidation catalysts and the production of green fuel

H Lv, YV Geletii, C Zhao, JW Vickers, G Zhu… - Chemical Society …, 2012 - pubs.rsc.org
In the last five years and currently, research on solar fuels has been intense and no sub-
area in this field has been more active than the development of water oxidation catalysts …

Deactivation in homogeneous transition metal catalysis: causes, avoidance, and cure

RH Crabtree - Chemical reviews, 2015 - ACS Publications
Deactivation leads to loss of catalyst activity or selectivity with increasing reaction time, but
has attracted less academic attention in homogeneous catalysis than is justified by its …

Design and development of photoanodes for water-splitting dye-sensitized photoelectrochemical cells

JR Swierk, TE Mallouk - Chemical Society Reviews, 2013 - pubs.rsc.org
Dye sensitized solar cells (DSSCs) use low-cost materials, feature tunable molecular
sensitizers, and exhibit quantum efficiencies near unity. These advantageous features can …

A Keggin Polyoxometalate Shows Water Oxidation Activity at Neutral pH: POM@ ZIF‐8, an Efficient and Robust Electrocatalyst

S Mukhopadhyay, J Debgupta, C Singh… - Angewandte …, 2018 - Wiley Online Library
Keggin‐type polyoxometalate anions [XM12O40] n− are versatile, as their applications in
interdisciplinary areas show. The Keggin anion [CoW12O40] 6− turns into an efficient and …