Although it is well known that aqueous electrolyte solutions behave non-ideally, few are so
non-ideal that adding an electrolyte to a saturated solution with a common ion enhances …

Ultraviolet (UV) photolysis of nitrite ions (NO 2−) in aqueous solutions produces a suite of
radicals, viz., NO·, O−,· OH, and· NO 2. The O− and NO· radicals are initially formed from the …

Predicting the behavior of oxyanions in radioactive waste stored at the Department of
Energy legacy nuclear sites requires the development of novel analytical methods. This …

The underlying mechanism by which tetrahedrally-coordinated aluminate solution species
react to precipitate octahedrally-coordinated Al 3+ in gibbsite is unknown. Sodium aluminate …

Understanding multiple lengthscale correlations in the pair distribution functions (PDFs) of
aq. electrolytes is a persistent challenge. Here, the coordination chemistry of polyoxoanions …

The solubility of sodium nitrite (NaNO2) in water is important to many industries, including
those of heat pumps, oil extraction, and the management of alkaline nuclear waste. This …

The dynamics, orientational anisotropy, diffusivity, viscosity, and density were measured for
concentrated lithium salt solutions, including lithium chloride (LiCl), lithium bromide (LiBr) …

Determining the diffusive properties of multicomponent electrolyte mixtures is challenging
because the compositional space is large. Here, this complexity was accounted for in …

While Zavitsas' hydration model has been used to determine the activity of water in
electrolyte solutions, it has not previously been demonstrated to model the activities of …

While iodine speciation is important for a wide range of nuclear safety activities,
understanding the mechanisms of the transformations of iodine between chemical forms and …