The lower the better: Efficient carbonylative reactions under atmospheric pressure of carbon monoxide

Q Tian, X Yin, R Sun, Y Li - Coordination Chemistry Reviews, 2023 - Elsevier
Carbon monoxide is an indispensable C1 building block that has been recognized as a
potent feedstock for synthesizing carbonyl-containing molecules. Carbonylative reactions …

Recent advances in the synthesis of pyrrolo [1, 2-a] indoles and their derivatives

YG Shelke, PE Hande, SJ Gharpure - Organic & Biomolecular …, 2021 - pubs.rsc.org
The pyrrolo [1, 2-a] indole unit is a privileged heterocycle found in numerous natural
products and has been shown to exhibit diverse pharmacological properties. Thus, recent …

No making without breaking: nitrogen-centered carbonylation reactions

Z Yin, JX Xu, XF Wu - ACS Catalysis, 2020 - ACS Publications
Carbonylation, an efficient and straightforward approach for installing a carbonyl group into
their parent compounds, is an important area in modern organic synthesis. This Review …

Rhodium (III)-Catalyzed Oxidative C–H Alkylation of Aniline Derivatives with Allylic Alcohols To Produce β-Aryl Ketones

SM Khake, N Chatani - ACS Catalysis, 2022 - ACS Publications
The Rh (III)-catalyzed C–H oxidative alkylation of aniline derivatives with readily available
secondary allyl alcohols using a pyrimidine-directing group, leading to the production of β …

Isoindolinone Synthesis via One‐Pot Type Transition Metal Catalyzed C− C Bond Forming Reactions

R Savela, C Méndez‐Gálvez - Chemistry–A European Journal, 2021 - Wiley Online Library
Isoindolinone structure is an important privileged scaffold found in a large variety of naturally
occurring as well as synthetic, biologically and pharmaceutically active compounds. Owing …

Rhodium-catalyzed selective oxidative (spiro) annulation of 2-arylindoles by using benzoquinone as a C2 or C1 synthon

S Guo, Y Liu, L Zhao, X Zhang, X Fan - Organic letters, 2019 - ACS Publications
Rhodium-catalyzed substrate-tunable oxidative annulation and spiroannulation reactions of
2-arylindoles with benzoquinone leading to 9 H-dibenzo [a, c] carbazol-3-ols and new …

One-Pot Synthesis of Furo[3,4-c]indolo[2,1-a]isoquinolines through Rh(III)-Catalyzed Cascade Reactions of 2-Phenylindoles with 4-Hydroxy-2-alkynoates

Y Liu, Z Yang, R Chauvin, W Fu, Z Yao, L Wang… - Organic …, 2020 - ACS Publications
An efficient and regioselective synthesis of fused polycyclic furo [3, 4-c] indolo [2, 1-a]
isoquinolines through Rh (III)-catalyzed cascade C–H activation/annulation/lactonization of …

Palladium-catalyzed direct C–H carbonylation of free primary benzylamines: A synthesis of benzolactams

C Zhang, Y Ding, Y Gao, S Li, G Li - Organic letters, 2018 - ACS Publications
A protocol for palladium-catalyzed C–H carbonylation of readily available free primary
benzylamines using NH2 as the chelating group under an atmospheric pressure of CO has …

Iridium-Catalyzed Tandem Dehydrogenation/Hydroarylation Approach to Synthetically Versatile C2-Alkenyl N–H Indoles

C Lázaro-Milla, JL Mascareñas, F López - ACS Catalysis, 2024 - ACS Publications
Readily available N-carbamoyl indolines can be converted into highly valuable 2-alkenyl
and 2-alkyl indoles in a one-pot reaction, through an autotandem catalytic cascade …

Cocrystal Formation Precedes the Mechanochemically Acetate‐Assisted C−H Activation with [Cp*RhCl2]2

KJ Ardila‐Fierro, M Rubčić… - Chemistry–A European …, 2022 - Wiley Online Library
This work reports the experimentally studied mechanochemical formation of rhodacycles by
ball milling pyridine‐and quinoline‐derived substrates and [Cp* RhCl2] 2 in the presence of …