Good computational practice in the assignment of absolute configurations by TDDFT calculations of ECD spectra

G Pescitelli, T Bruhn - Chirality, 2016 - Wiley Online Library
Quantum‐mechanical calculations of chiroptical properties have rapidly become the most
popular method for assigning absolute configurations (AC) of organic compounds, including …

Synthetic chlorins, possible surrogates for chlorophylls, prepared by derivatization of porphyrins

M Taniguchi, JS Lindsey - Chemical reviews, 2017 - ACS Publications
Chlorophylls make Earth green, are the central constituents in the engine of photosynthesis,
and not surprisingly have garnered immense attention. A chlorin, the core chromophore of a …

Optically active porphyrin and phthalocyanine systems

H Lu, N Kobayashi - Chemical reviews, 2016 - ACS Publications
This review highlights and summarizes various optically active porphyrin and
phthalocyanine molecules prepared using a wide range of structural modification methods …

Metal complexes of porphyrinoids containing nonpyrrolic heterocycles

DW Thuita, C Brückner - Chemical Reviews, 2022 - ACS Publications
The replacement of one or more pyrrolic building block (s) of a porphyrin by a nonpyrrolic
heterocycle leads to the formation of so-called pyrrole-modified porphyrins (PMPs) …

The Breaking and Mending of meso-Tetraarylporphyrins: Transmuting the Pyrrolic Building Blocks

C Bruckner - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Naturally occurring porphyrins and hydroporphyrins vary with respect to their
ring substituents and oxidation states, but their tetrapyrrolic frameworks remain fully …

[PDF][PDF] Syntheses of bacteriochlorins and isobacteriochlorins

C Brückner, L Samankumara… - Handbook of porphyrin …, 2012 - academia.edu
Porphyrins are fully unsaturated tetrapyrrolic macrocycles linked by methylene carbons. The
chemical and physical properties of porphyrins are mainly determined by the presence of a …

Direct Oxidations of meso-Tetrakis(pentafluorophenyl)porphyrin: Porphotrilactones and Entry into a Nonbiological Porphyrin Degradation Pathway

N Hewage, D Damunupola, M Zeller… - The Journal of Organic …, 2024 - ACS Publications
The direct oxidations of meso-tetrakis (pentafluorophenyl) porphyrin using
cetyltrimethylammonium permanganate (CTAP), RuCl3/Oxone/base or Ag+/oxalic acid each …

Ytterbium (III) Porpholactones: β‐Lactonization of Porphyrin Ligands Enhances Sensitization Efficiency of Lanthanide Near‐Infrared Luminescence

XS Ke, BY Yang, X Cheng, SLF Chan… - … –A European Journal, 2014 - Wiley Online Library
The near‐infrared (NIR) luminescence efficiency of lanthanide complexes is largely
dependent on the electronic and photophysical properties of antenna ligands. Although …

Porphyrin macrocycle modification: Pyrrole ring-contracted or-expanded porphyrinoids

LD Costa, JIT Costa, AC Tomé - Molecules, 2016 - mdpi.com
In recent years, several synthetic strategies aiming at the peripheral functionalization of
porphyrins were developed. Particularly interesting are those involving the modification of β …

meso-Arylporpholactones and their Reduction Products

C Brückner, J Ogikubo, JR McCarthy… - The Journal of …, 2012 - ACS Publications
The rational syntheses of meso-tetraaryl-3-oxo-2-oxaporphyrins 5, known as
porpholactones, via MnO4–-mediated oxidations of the corresponding meso-tetraaryl-2, 3 …