Catalytic organic reactions in water toward sustainable society

T Kitanosono, K Masuda, P Xu, S Kobayashi - Chemical reviews, 2018 - ACS Publications
Traditional organic synthesis relies heavily on organic solvents for a multitude of tasks,
including dissolving the components and facilitating chemical reactions, because many …

Parahydrogen‐based hyperpolarization for biomedicine

JB Hövener, AN Pravdivtsev, B Kidd… - Angewandte Chemie …, 2018 - Wiley Online Library
Magnetic resonance (MR) is one of the most versatile and useful physical effects used for
human imaging, chemical analysis, and the elucidation of molecular structures. However, its …

Instrumentation for hydrogenative parahydrogen-based hyperpolarization techniques

AB Schmidt, CR Bowers, K Buckenmaier… - Analytical …, 2022 - ACS Publications
The unique properties of the entangled, antisymmetric nuclear spin state of dihydrogen,
parahydrogen (pH2), has intrigued physicists, chemists, and other scientists for almost a …

A leap forward in iridium–NHC catalysis: new horizons and mechanistic insights

M Iglesias, LA Oro - Chemical Society Reviews, 2018 - pubs.rsc.org
This review summarises the most recent advances in Ir–NHC catalysis while revisiting all the
classical reactions in which this type of catalyst has proved to be active. The influence of the …

Heterogeneous Catalysis and Parahydrogen‐Induced Polarization

EV Pokochueva, DB Burueva, OG Salnikov… - …, 2021 - Wiley Online Library
Parahydrogen‐induced polarization with heterogeneous catalysts (HET‐PHIP) has been a
subject of extensive research in the last decade since its first observation in 2007. While …

Synergies between hyperpolarized NMR and microfluidics: a review

J Eills, W Hale, M Utz - Progress in Nuclear Magnetic Resonance …, 2022 - Elsevier
Hyperpolarized nuclear magnetic resonance and lab-on-a-chip microfluidics are two
dynamic, but until recently quite distinct, fields of research. Recent developments in both …

Silica‐Encapsulated Pt‐Sn Intermetallic Nanoparticles: A Robust Catalytic Platform for Parahydrogen‐Induced Polarization of Gases and Liquids

EW Zhao, R Maligal‐Ganesh, C Xiao… - Angewandte …, 2017 - Wiley Online Library
Recently, a facile method for the synthesis of size‐monodisperse Pt, Pt3Sn, and PtSn
intermetallic nanoparticles (iNPs) that are confined within a thermally robust mesoporous …

Strong Metal–Support Interactions Enhance the Pairwise Selectivity of Parahydrogen Addition over Ir/TiO2

EW Zhao, H Zheng, K Ludden, Y Xin… - Acs …, 2016 - ACS Publications
The effects of strong metal–support interactions (SMSI) on the pairwise selectivity of propene
hydrogenation over metal-oxide-supported Ir nanoparticles were investigated using …

A New Ir‐NHC Catalyst for Signal Amplification by Reversible Exchange in D2O

P Spannring, I Reile, M Emondts… - … A European Journal, 2016 - Wiley Online Library
NMR signal amplification by reversible exchange (SABRE) has been observed for pyridine,
methyl nicotinate, N‐methylnicotinamide, and nicotinamide in D2O with the new catalyst [Ir …

Liquid-state carbon-13 hyperpolarization generated in an MRI system for fast imaging

AB Schmidt, S Berner, W Schimpf, C Müller… - Nature …, 2017 - nature.com
Hyperpolarized (HP) tracers dramatically increase the sensitivity of magnetic resonance
imaging (MRI) to monitor metabolism non-invasively and in vivo. Their production, however …