Destruction of metal–organic frameworks: positive and negative aspects of stability and lability

L Feng, KY Wang, GS Day, MR Ryder… - Chemical …, 2020 - ACS Publications
Metal–organic frameworks (MOFs), constructed from organic linkers and inorganic building
blocks, are well-known for their high crystallinity, high surface areas, and high component …

Metal–organic frameworks against toxic chemicals

T Islamoglu, Z Chen, MC Wasson, CT Buru… - Chemical …, 2020 - ACS Publications
Materials capable of the safe and efficient capture or degradation of toxic chemicals,
including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are …

A ligand insertion mechanism for cooperative NH3 capture in metal–organic frameworks

BER Snyder, AB Turkiewicz, H Furukawa, MV Paley… - Nature, 2023 - nature.com
Ammonia is a critical chemical in agriculture and industry that is produced on a massive
scale via the Haber–Bosch process. The environmental impact of this process, which uses …

Adsorbent materials for ammonium and ammonia removal: A review

B Han, C Butterly, W Zhang, J He, D Chen - Journal of Cleaner Production, 2021 - Elsevier
Abstract Ammonium (NH 4+) and ammonia (NH 3) are notorious hard-to-treat pollutants,
leading to serious deterioration of aquatic ecosystems and significant risks to human health …

Ionic liquid hybrid metal–organic frameworks for efficient adsorption and selective separation of ammonia at high temperature

Z Li, Y Chen, Z Wang, Y Zhao, Q Xia, J Qiu… - Chemical Engineering …, 2023 - Elsevier
Efficient adsorption and selective separation of ammonia at high temperature is a crucial
and challenging issue. In this work, a series of stable ionic liquid hybrid materials have been …

Ammonia as an alternative fuel for vehicular applications: Paving the way for adsorbed ammonia and direct ammonia fuel cells

M Sonker, SK Tiwary, N Shreyash, S Bajpai… - Journal of Cleaner …, 2022 - Elsevier
This article is a roadmap for researchers in this field to look for an efficient and reliable
alternative for fossil fuels in the form of ammonia. We have discussed different storage …

Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents

NS Bobbitt, ML Mendonca, AJ Howarth… - Chemical Society …, 2017 - pubs.rsc.org
Owing to the vast diversity of linkers, nodes, and topologies, metal–organic frameworks can
be tailored for specific tasks, such as chemical separations or catalysis. Accordingly, these …

Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture

AJ Rieth, AM Wright, M Dincă - Nature Reviews Materials, 2019 - nature.com
Metal–organic frameworks (MOFs) have diverse applications involving the storage,
separation and sensing of weakly interacting, high-purity gases. Exposure to impure gas …

Metal-organic frameworks for energy conversion and water harvesting: A bridge between thermal engineering and material science

LG Gordeeva, YD Tu, Q Pan, ML Palash, BB Saha… - Nano Energy, 2021 - Elsevier
Abstract Adsorption technologies for Heat Conversion (AHC) and Water Harvesting (AWH)
hold great potential for energy management because they can utilize renewable energy or …

Controlled gas uptake in metal–organic frameworks with record ammonia sorption

AJ Rieth, M Dincă - Journal of the American Chemical Society, 2018 - ACS Publications
Ammonia is a vital commodity in our food supply chain, but its toxicity and corrosiveness
require advanced protection and mitigation. These needs are not met efficiently by current …