Abstract Hydrogen peroxide (H 2 O 2) is an environmentally friendly versatile oxidant, which
has been used in chemical industry, medical, energy, and environmental fields …

Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

Atomically monodispersed heterogeneous catalysts with uniform active sites and high atom
utilization efficiency are ideal heterogeneous catalytic materials. Designing such type of …

Heterogeneous metal oxide catalysts are widely studied for the aerobic oxidations of C1–C4
alkanes to form olefins and oxygenates. In this review, we outline the properties of supported …

Polyoxometalates (POMs) have attracted considerable attention as an important class of
proton-conductive materials since POMs can efficiently transport protons due to their small …

Electrochemical oxygen reduction offers an efficient and environmentally friendly route for
hydrogen peroxide (H2O2) generation. This electrochemical process can produce H2O2 on …

Cluster catalysts are attractive for their atomically precise structures, defined compositions,
tunable coordination environments, uniform active sites, and their ability to transfer multiple …

Given the large amount of anthropogenic CO2 emissions, it is advantageous to use CO2 as
feedstock for the fabrication of everyday products, such as fuels and materials. An attractive …

Polyoxometalates represent a diverse range of molecular clusters with an almost unmatched
range of physical properties and the ability to form structures that can bridge several length …

In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …