Deep eutectic solvents: A review of fundamentals and applications

BB Hansen, S Spittle, B Chen, D Poe, Y Zhang… - Chemical …, 2020 - ACS Publications
Deep eutectic solvents (DESs) are an emerging class of mixtures characterized by
significant depressions in melting points compared to those of the neat constituent …

Current research trends in dielectric relaxation studies of amorphous pharmaceuticals: Physical stability, tautomerism, and the role of hydrogen bonding

J Knapik-Kowalczuk, M Rams-Baron… - TrAC Trends in Analytical …, 2021 - Elsevier
Alarming statistics showing the continuous increase in the number of drugs and drug
candidates with insufficient water-solubility focus scientist's efforts on finding optimal strategy …

Nature of dielectric response of phenyl alcohols

M Tarnacka, A Czaderna-Lekka… - The Journal of …, 2023 - ACS Publications
Phenyl alcohols (PhAs) are an interesting class of materials, for which the dielectric
response reveals only the presence of single prominent Debye-like (D) relaxation …

Slow rheological mode in glycerol and glycerol–water mixtures

MH Jensen, C Gainaru, C Alba-Simionesco… - Physical Chemistry …, 2018 - pubs.rsc.org
Glycerol–water mixtures were studied at molar concentrations ranging from xgly= 1 (neat
glycerol) to xgly= 0.3 using shear mechanical spectroscopy. We observed a low frequency …

Influence of molecular architecture on the dynamics of H-bonded supramolecular structures in phenyl-propanols

T Böhmer, JP Gabriel, T Richter, F Pabst… - The Journal of …, 2019 - ACS Publications
Relaxation behavior of monohydroxy alcohols (monoalcohols) in broadband dielectric
spectroscopy (BDS) is usually dominated by the Debye process. This process is regarded as …

Are hydrogen supramolecular structures being suppressed upon nanoscale confinement? The case of monohydroxy alcohols

A Talik, M Tarnacka, M Geppert-Rybczyńska… - Journal of colloid and …, 2020 - Elsevier
In this paper, the molecular dynamics, H-bonding pattern and wettability of the primary and
secondary monohydroxyalcohols, 2-ethyl-1-hexanol (2E1H), 2-ethyl-1-butanol (2E1B) and 5 …

Simultaneously measuring the dichroism and the dielectric response of an azobenzene-doped organic glass former

E Dzik, P Datin, JP Dognon, C Fajolles… - Review of Scientific …, 2023 - pubs.aip.org
We have designed an experimental setup allowing to simultaneously measure both the
dielectric response of a supercooled liquid and the dynamics of azobenzene chromophores …

Influence of hydrogen bonding on the kinetic stability of vapor-deposited glasses of triazine derivatives

A Laventure, A Gujral, O Lebel, C Pellerin… - The Journal of …, 2017 - ACS Publications
It has recently been established that physical vapor deposition (PVD) can produce organic
glasses with enhanced kinetic stability, high density, and anisotropic packing, with the …

Correlation between locally ordered (hydrogen-bonded) nanodomains and puzzling dynamics of polymethysiloxane derivative

M Tarnacka, K Jurkiewicz, B Hachuła… - …, 2020 - ACS Publications
We examined the behavior of poly (mercaptopropyl) methylsiloxane (PMMS), characterized
by a polymer chain backbone of alternate silicon and oxygen atoms substituted by a polar …

[HTML][HTML] Tuning the dynamics of imidazolium-based ionic liquids via hydrogen bonding. I. The viscous regime

CA Thomann, P Münzner, K Moch… - The Journal of …, 2020 - pubs.aip.org
Combining results from impedance spectroscopy and oscillatory shear rheology, the present
work focuses on the relation between the mass and charge flows and on how these are …