London dispersion in molecular chemistry—reconsidering steric effects

JP Wagner, PR Schreiner - Angewandte Chemie International …, 2015 - Wiley Online Library
London dispersion, which constitutes the attractive part of the famous van der Waals
potential, has long been underappreciated in molecular chemistry as an important element …

London'sche Dispersionswechselwirkungen in der Molekülchemie–eine Neubetrachtung sterischer Effekte

JP Wagner, PR Schreiner - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Die London'sche Dispersion, die den attraktiven Teil des Van‐der‐Waals‐
Potentials beschreibt, wurde lange als Element struktureller Stabilität in der molekularen …

Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study

WB Liu, DP Schuman, YF Yang… - Journal of the …, 2017 - ACS Publications
We recently reported a new method for the direct dehydrogenative C–H silylation of
heteroaromatics utilizing Earth-abundant potassium tert-butoxide. Herein we report a …

Toward a consistent interpretation of the QTAIM: tortuous link between chemical bonds, interactions, and bond/line paths

C Foroutan‐Nejad, S Shahbazian… - Chemistry–A European …, 2014 - Wiley Online Library
Currently, bonding analysis of molecules based on the Quantum Theory of Atoms in
Molecules (QTAIM) is popular; however,“misinterpretations” of the QTAIM analysis are also …

Phase-Dependence of Molecular Structures Arising from Weak London Dispersion Interactions

NW Mitzel, JH Lamm - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus The structures of molecules can be different in different phases. Intermolecular
forces, even those of weak noncovalent interactions (WNCIs), can lead to a preference for …

Steric crowding in tetrel bonds

S Scheiner - The Journal of Physical Chemistry A, 2018 - ACS Publications
The tetravalent character of tetrel atoms leaves only limited room for an incoming
nucleophile to approach and engage in a noncovalent bond with a tetrel atom. Any such …

The Nature of Chalcogen‐Bonding‐Type Tellurium–Nitrogen Interactions: A First Experimental Structure from the Gas Phase

T Glodde, YV Vishnevskiy… - Angewandte Chemie …, 2021 - Wiley Online Library
Abstract (C6F5) Te (CH2) 3NMe2 (1), a perfluorophenyltellurium derivative capable of
forming intramolecular N⋅⋅⋅ Te interactions, was prepared and characterized. The donor …

Ability of IR and NMR spectral data to distinguish between a tetrel bond and a hydrogen bond

S Scheiner - The Journal of Physical Chemistry A, 2018 - ACS Publications
The placement of a nucleophile X along the R-CH3 axis of a methyl group can be described
as either a trifurcated H bond or as a tetrel bond between C and X. Quantum calculations of …

Strongly Bound π‐Hole Tetrel Bonded Complexes between H2SiO and Substituted Pyridines. Influence of Substituents

S Bhattarai, D Sutradhar, AK Chandra - ChemPhysChem, 2022 - Wiley Online Library
Ab initio calculation at the MP2/aug‐cc‐pVTZ level has been performed on the π‐hole
based N… Si tetrel bonded complexes between substituted pyridines and H2SiO. The …

Silver and Gold Complexes with a New 1, 10‐Phenanthroline Analogue N‐Heterocyclic Carbene: A Combined Structural, Theoretical, and Photophysical Study

M Kriechbaum, M List, R JF Berger… - … A European Journal, 2012 - Wiley Online Library
Transition-metal complexes with 1, 10-phenanthroline (phen) ligands frequently reveal
interesting photo-and electroluminescence properties, and thus are well suited for …