Abstract Die London'sche Dispersion, die den attraktiven Teil des Van‐der‐Waals‐ Potentials beschreibt, wurde lange als Element struktureller Stabilität in der molekularen …
WB Liu, DP Schuman, YF Yang… - Journal of the …, 2017 - ACS Publications
We recently reported a new method for the direct dehydrogenative C–H silylation of heteroaromatics utilizing Earth-abundant potassium tert-butoxide. Herein we report a …
Currently, bonding analysis of molecules based on the Quantum Theory of Atoms in Molecules (QTAIM) is popular; however,“misinterpretations” of the QTAIM analysis are also …
NW Mitzel, JH Lamm - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus The structures of molecules can be different in different phases. Intermolecular forces, even those of weak noncovalent interactions (WNCIs), can lead to a preference for …
S Scheiner - The Journal of Physical Chemistry A, 2018 - ACS Publications
The tetravalent character of tetrel atoms leaves only limited room for an incoming nucleophile to approach and engage in a noncovalent bond with a tetrel atom. Any such …
Abstract (C6F5) Te (CH2) 3NMe2 (1), a perfluorophenyltellurium derivative capable of forming intramolecular N⋅⋅⋅ Te interactions, was prepared and characterized. The donor …
S Scheiner - The Journal of Physical Chemistry A, 2018 - ACS Publications
The placement of a nucleophile X along the R-CH3 axis of a methyl group can be described as either a trifurcated H bond or as a tetrel bond between C and X. Quantum calculations of …
Ab initio calculation at the MP2/aug‐cc‐pVTZ level has been performed on the π‐hole based N… Si tetrel bonded complexes between substituted pyridines and H2SiO. The …
M Kriechbaum, M List, R JF Berger… - … A European Journal, 2012 - Wiley Online Library
Transition-metal complexes with 1, 10-phenanthroline (phen) ligands frequently reveal interesting photo-and electroluminescence properties, and thus are well suited for …