From carbonyls to π-aromatic arenes: A thirty years journey through organometallic technetium chemistry

R Alberto - Journal of Organometallic Chemistry, 2023 - Elsevier
This account briefly summarizes the organometallic chemistry of technetium over the thirty
years of experience made by the author and others. Earlier publications, many from the" …

Substituent Effect versus Aromaticity─ A Curious Case of Fulvene Derivatives

PA Wieczorkiewicz, KK Zborowski… - The Journal of …, 2023 - ACS Publications
A computational study on amino-and nitro-substituted penta-and heptafulvenes reveals the
interplay between the aromaticity and the substituent effect (SE). Ring substitution alone has …

Palladium-Catalyzed Synthesis of 3, 6-Diaryl-1-silylfulvenes: A Promising Entry for Preparing 1, 3, 6-Triarylfulvenes Bearing Three Different Aryl Groups

H Ohki, H Kinoshita, K Miura - Organic Letters, 2023 - ACS Publications
We developed a synthetic methodology for preparing (E)-1, 3, 6-triarylfulvenes bearing three
different aryl groups. The reaction of 1, 4-diaryl-1-bromo-1, 3-butadienes with silylacetylenes …