This perspective review will examine the coordination chemistry and applications of metal
complexes of 4, 5-diazafluorene derivatives. The versatile derivatives of 4, 5-diazafluorene …

Metal–ligand cooperativity is a powerful tool for the activation of various bonds but has
rarely, if ever, been studied with the radioactive transition metal 99Tc. In this work, we …

Zinc (II) and cadmium (II) chlorido complexes with an N, N-chelating nopinane-annelated 4,
5-diazafluoren-9-one ligand (LO) were synthesized. While the zinc (II) complex is …

A bis (diphenyl)‐phosphine functionalized β‐diketimine (PNac‐H) was synthesized as a
flexible ligand for transition metal complexes. The newly designed ligand features …

Abstract Ligands based upon the 4, 5‐diazafluorene core are an important class of
emerging ligands in organometallic chemistry, but the structure and electronic properties of …

The improved catalytic conditions and detailed reaction mechanism of the visible-light driven
hydrocarboxylation of alkenes with CO2 by the Rh (I) and photoredox dual catalysts were …

We describe rhenium (I) triscarbonyl compounds (3 and 4) decorated with simple-to-use 2-
iminomethyl-pyridine (1, impy) and 2-aminomethyl-pyridine (2, ampy) ligands, respectively …

Recently, a new artificial carbonic anhydrase enzyme in which the native zinc cation has
been replaced with a Rh (I) has been proposed as a new reductase that is able to efficiently …

We report the synthesis and characterization of Ru (II) and V (III) 4, 5-diazafluorene
derivatives, and their respective reactivity towards B–H bonds. A Ru (II) hydride dinitrogen …

New strategies for the reforming of methanol under mild conditions on the basis of
heterogeneous and molecular catalysts have raised the hopes and expectations on this fuel …