Titanium catalysis for the synthesis of fine chemicals–development and trends

M Manßen, LL Schafer - Chemical Society Reviews, 2020 - pubs.rsc.org
Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …

Group 1 and 2 and early transition metal complexes bearing N-heterocyclic carbene ligands: coordination chemistry, reactivity, and applications

S Bellemin-Laponnaz, S Dagorne - Chemical Reviews, 2014 - ACS Publications
N-Heterocyclic carbenes (NHCs) are omnipresent ligands in coordination and
organometallic chemistry, which is reflected by myriads of applications involving NHC …

High-Oxidation-State 3d Metal (Ti–Cu) Complexes with N-Heterocyclic Carbene Ligation

J Cheng, L Wang, P Wang, L Deng - Chemical reviews, 2018 - ACS Publications
High-oxidation-state 3d metal species have found a wide range of applications in modern
synthetic chemistry and materials science. They are also implicated as key reactive species …

Multidentate N-heterocyclic carbene complexes of the 3d metals: Synthesis, structure, reactivity and catalysis

V Charra, P de Fremont, P Braunstein - Coordination Chemistry Reviews, 2017 - Elsevier
N-Heterocyclic carbene (NHC) ligands are attracting worldwide interest because of their
considerable scope and potential in coordination/organometallic chemistry, catalysis and …

N-heterocyclic carbene (NHC) complexes of group 4 transition metals

D Zhang, G Zi - Chemical Society Reviews, 2015 - pubs.rsc.org
Since the discovery of a stable N-heterocyclic carbene (NHC), the use of NHCs in chemistry
has developed rapidly over the past two decades. These interesting compounds are …

Recent developments in alkene hydro-functionalisation promoted by homogeneous catalysts based on earth abundant elements: formation of C–N, C–O and C–P …

V Rodriguez-Ruiz, R Carlino… - Dalton …, 2015 - pubs.rsc.org
This Perspective article provides an overview of the recent advancements in the field of intra-
and inter-molecular C–N, C–O and C–P bond formation by hydroamination …

NHC-based pincer ligands: carbenes with a bite

RE Andrew, L González-Sebastián, AB Chaplin - Dalton transactions, 2016 - pubs.rsc.org
In this frontier article we overview the emergence and scope of NHC-based CCC and CNC
pincer systems, ie complexes containing mer-tridentate ligands bearing two NHC donor …

Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co (iii) complexes and initial hydroboration trials

SW Reilly, CE Webster, TK Hollis, HU Valle - Dalton Transactions, 2016 - pubs.rsc.org
Development of CCC-NHC pincer Co complexes via transmetalation from Zr is reported.
Formation of these air-stable Co (III) complexes was achieved through use of a CoCl2 or Co …

Efficient near-UV emitters based on cationic bis-pincer iridium (III) carbene complexes

N Darmawan, CH Yang, M Mauro, M Raynal… - Inorganic …, 2013 - ACS Publications
We report on the photophysical studies of two cationic near-UV emitters based on bis-pincer
Ir (III) carbene complexes:[Ir n Bu (CNHCMeCCNHC) 2] X, where Ir n Bu (CNHCMeCCNHC) …

CCC–pincer–NHC osmium complexes: New types of blue-green emissive neutral compounds for organic light-emitting devices (OLEDs)

RG Alabau, B Eguillor, J Esler, MA Esteruelas… - …, 2014 - ACS Publications
Novel homoleptic and heteroleptic NHC carbene containing bis (tridentate) osmium (II)
complexes have been designed, synthesized, and characterized, and their photophysical …