Post-synthetic modifications of metal–organic cages

J Liu, Z Wang, P Cheng, MJ Zaworotko… - Nature Reviews …, 2022 - nature.com
Metal–organic cages (MOCs) are discrete, supramolecular entities that consist of metal
nodes and organic linkers, which can offer solution processability and high porosity …

The chemistry of multi-component and hierarchical framework compounds

L Feng, KY Wang, GS Day, HC Zhou - Chemical Society Reviews, 2019 - pubs.rsc.org
Multi-component hierarchically porous materials are an emerging class of materials with
tailored compositions, tunable distribution and sophisticated applications. An increasing …

A (macro) molecular-level understanding of polymer network topology

Y Gu, J Zhao, JA Johnson - Trends in Chemistry, 2019 - cell.com
Topology plays a critical role in dictating the properties of many materials. In recent years,
with advances in synthetic and characterization techniques, substantial efforts have been …

Identification of a Heteroleptic Pd6L6L′6 Coordination Cage by Screening of a Virtual Combinatorial Library

S Sudan, RJ Li, SM Jansze, A Platzek… - Journal of the …, 2021 - ACS Publications
The design of structurally defined heteroleptic coordination cages is a challenging task, and
only few examples are known to date. Here we describe a selection approach that allowed …

When polymerization meets coordination-driven self-assembly: metallo-supramolecular polymers based on supramolecular coordination complexes

Y Zhu, W Zheng, W Wang, HB Yang - Chemical Society Reviews, 2021 - pubs.rsc.org
Polymers have greatly changed and are still changing the way we live ever since, and the
construction of novel polymers as functional materials remains an attractive topic in polymer …

Metallogels: availability, applicability, and advanceability

H Wu, J Zheng, AL Kjøniksen, W Wang… - Advanced …, 2019 - Wiley Online Library
Introducing metal components into gel matrices provides an effective strategy to develop soft
materials with advantageous properties such as: optical activity, conductivity, magnetic …

Endohedrally functionalized metal–organic cage-cross-linked polymer gels as modular heterogeneous catalysts

CM Brown, DJ Lundberg, JR Lamb… - Journal of the …, 2022 - ACS Publications
The immobilization of homogeneous catalysts onto supports to improve recyclability while
maintaining catalytic efficiency is often a trial-and-error process limited by poor control of the …

Characterizing polymer structure with small-angle neutron scattering: A Tutorial

Y Wei, MJA Hore - Journal of Applied Physics, 2021 - pubs.aip.org
Small-angle neutron scattering (SANS) is a powerful technique that has been widely used to
study polymer materials. In particular, it can provide information on the size, shape, and …

Polymers on nanoparticles: structure & dynamics

MJA Hore - Soft Matter, 2019 - pubs.rsc.org
Grafting polymers to nanoparticle surfaces influences properties from the conformation of the
polymer chains to the dispersion and assembly of nanoparticles within a polymeric material …

Orientational self-sorting in cuboctahedral Pd cages

RJ Li, A Tarzia, V Posligua, KE Jelfs, N Sanchez… - Chemical …, 2022 - pubs.rsc.org
Cuboctahedral coordination cages of the general formula [Pd12L24] 24+(L= low-symmetry
ligand) were analyzed theoretically and experimentally. With 350 696 potential isomers, the …