The world of modified porphyrins changed forever when an N-confused porphyrin (NCP), a
porphyrin isomer, was first published in 1994. The replacement of one inner nitrogen with a …

This Review outlines the progress in the field of synthetic expanded carbaporphyrinoids.
The evolution of this topic is demonstrated with expanded porphyrin‐inspired systems with a …

The analogue of octaphyrin (1.1. 1.0. 1.1. 1.0) bearing two dimethoxyphenanthrene units
was synthesized and characterized in solution and solid state. The macrocycle was …

The unique environment within the core of carbaporphyrinoid systems provides a platform to
explore unusual organometallic chemistry. The ability of these structures to form stable …

Abstract Di‐2, 7‐naphthihexaphyrin (1.1. 1.1. 1.1), a non‐aromatic carba‐analogue of the
hexaphyrin (1.1. 1.1. 1.1), incorporating two built‐in 2, 7‐naphthylene moieties was …

Synthesis of an azacoronene, in which both pyrrole and azulene moieties are circularly
fused, was achieved just in three steps. This new azacoronene exhibited multistep …

Anfinsen's dogma that sequence dictates structure is fundamental to understanding the
activity and assembly of proteins. This idea has been applied to all manner of oligomers but …

The reaction of a carbatripyrrin with a tellurophene dicarbinol in the presence of BF3· Et2O,
followed by oxidation with DDQ, afforded the first example of a telluracarbaporphyrin …

Fluorene‐based tripyrrane has been used as a fused precursor to synthesize three novel
examples of nonaromatic meso‐fused thia and selenabenzihomoporphyrin (2.1. 1.1) s by …

Core-modified porphyrins have been widely investigated and exhibit diverse characteristics.
Heteroporphyrins of this type retain the framework found in true porphyrins but have O, S …