In the wide area of host–guest chemistry, hemicryptophanes, combining a cyclotribenzylene
(or cyclotriveratrylene CTV) unit with another different C 3-symmetrical moiety, appears as a …

In this review we cover various approaches to meta-and paracyclophanes involving popular
reactions. Generally, we have included a strategy where the reaction was used for …

Biomimetic carbohydrate receptors (“synthetic lectins”) have potential as agents for
biological research and medicine. However, although effective strategies are available for …

In this study, we synthesized two cryptands featuring entangled tri-and tetra (ethylene glycol)
linkers. The cryptand bearing short linkers was chiral without any asymmetric carbon atoms …

Glucose is a key biomedical analyte, especially relevant to the management of diabetes.
Current methods for glucose determination rely on the enzyme glucose oxidase, requiring …

A captivating challenge in chemistry lies in achieving robust and precise binding of
uncharged, hydrophilic carbohydrate entities. Although past decades have provided a …

Here, we report a new and diversity-oriented approach to macrocyclic cyclophanes by a
Grignard reaction, followed by Fischer indolization and ring-closing metathesis (RCM) as …

The synthesis of eight enantiopure molecular cages (four diastereomeric pairs of
enantiomers) comprising a helically chiral cyclotriveratrylene (CTV) unit, three axially chiral …

The synthesis, characterization, and chiroptical properties of a new class of
hemicryptophanes combining a phosphine moiety and a cyclotriveratrylene unit are …

A convenient and efficient gram‐scale synthesis for enantiopure hemicryptophane–tren
(tren= tris (2‐aminoethyl) amine) derivatives has been developed. The four‐step synthesis is …