Small inorganic rings in the 21st century: From fleeting intermediates to novel isolable entities
Cyclic structures represent a well-studied structural class due to the novel bonding modes
and reactivity these units possess and the ubiquitous role of cyclic intermediates in a wide …
and reactivity these units possess and the ubiquitous role of cyclic intermediates in a wide …
Organobismuth (III) dihalides with T-shaped geometry stabilized by intramolecular N→ Bi interactions and related diorganobismuth (III) halides
AP Soran, C Silvestru, HJ Breunig, G Balázs… - …, 2007 - ACS Publications
Organobismuth (III) compounds containing (N, C, N)-pincer ligands were prepared and
characterized both in solution and in the solid state. Compound RBiCl2 1 [R= 2, 6 …
characterized both in solution and in the solid state. Compound RBiCl2 1 [R= 2, 6 …
Synthesis, structure, and reactivity of intramolecularly coordinated organoantimony and organobismuth sulfides
M Chovancova, R Jambor, A Ruzicka, R Jirasko… - …, 2009 - ACS Publications
Organoantimony (III) and organobismuth (III) sulfides, containing O, C, O-chelating ligands
(L1− 3= 2, 6-(ROCH2) 2C6H3−, where R= Me (L1), t-Bu (L2), or mesityl (L3)),[L1− 3MS] 2 …
(L1− 3= 2, 6-(ROCH2) 2C6H3−, where R= Me (L1), t-Bu (L2), or mesityl (L3)),[L1− 3MS] 2 …
Hypervalent organobismuth (III) carbonate, chalcogenides and halides with the pendant arm ligands 2-(Me 2 NCH 2) C 6 H 4 and 2, 6-(Me 2 NCH 2) 2 C 6 H 3
HJ Breunig, L Königsmann, E Lork, M Nema… - Dalton …, 2008 - pubs.rsc.org
R2BiOH (1)[R= 2-(Me2NCH2) C6H4] and (R2Bi) 2O (2) are formed by hydrolysis of R2BiCl
with KOH. Single crystals of 2 were obtained by air oxidation of (R2Bi) 2. The reaction of …
with KOH. Single crystals of 2 were obtained by air oxidation of (R2Bi) 2. The reaction of …
Monoorganobismuth (iii) dihalides containing the new pincer 2, 6-{MeN (CH 2 CH 2) 2 NCH 2} 2 C 6 H 3 ligand: solution NMR, vibrational and single-crystal X-ray …
The reaction of RLi [R= 2, 6-{MeN (CH2CH2) 2NCH2} 2C6H3] with BiCl3 (1: 1 molar ratio)
afforded RBiCl2 (2). RBiBr2 (3) and RBiI2 (4) were obtained by halogen-exchange reactions …
afforded RBiCl2 (2). RBiBr2 (3) and RBiI2 (4) were obtained by halogen-exchange reactions …
Reaktionen eines Dibismutans und von Cyclobismutanen mit Metallcarbonylen‐Synthesen von Komplexen mit R2Bi‐, RBi‐, Bi2‐und Bin‐Liganden (R= Me3CCH2 …
L Balazs, HJ Breunig, E Lork - Zeitschrift für anorganische und …, 2004 - Wiley Online Library
Abstract Reaktionen von [Fe2 (CO) 9] mit [(Me3CCH2) 2Bi] 2 oder cyclo‐(Me3SiCH2Bi) n
(n= 3‐5) führen zu den Komplexen [(R2Bi) 2Fe (CO) 4],[RBiFe (CO) 4] 2 (R= Me3CCH2 …
(n= 3‐5) führen zu den Komplexen [(R2Bi) 2Fe (CO) 4],[RBiFe (CO) 4] 2 (R= Me3CCH2 …
N→ As intramolecularly coordinated organoarsenic (III) chalcogenides: Isolation of terminal As–S and As–Se bonds
J Vrána, R Jambor, A Růžička, A Lyčka… - Journal of …, 2013 - Elsevier
Unprecedented NCN–intramolecularly chelated organoarsenic (III) sulfide and selenide
LAsE (where L=[2, 6-(Me2NCH2) 2C6H3]− and E= S (2) or Se (3)) were prepared by the …
LAsE (where L=[2, 6-(Me2NCH2) 2C6H3]− and E= S (2) or Se (3)) were prepared by the …
Theoretical Study of Structure, Bonding, and Electronic Behavior of Low-Valent Bismuth Cyclopentadienyl and Pentamethylcyclopentadienyl Half-Sandwich …
KY Monakhov, G Linti - Inorganic chemistry, 2009 - ACS Publications
The correlations between structural and electronic properties of the bismuth
cyclopentadienyl complexes of the types [(C5R5) n Bi n] q+(where R= H, Me; n= 1, q= 2; n …
cyclopentadienyl complexes of the types [(C5R5) n Bi n] q+(where R= H, Me; n= 1, q= 2; n …
Main‐Group Rings, Chains, and Polymer Compounds
KM Rabanzo‐Castillo, EM Leitao - Encyclopedia of Inorganic …, 2011 - Wiley Online Library
Although research in the field of main‐group rings, chains, and polymers is a less mature
area of chemistry than that of carbon‐based rings, chains, and polymers, it is currently very …
area of chemistry than that of carbon‐based rings, chains, and polymers, it is currently very …
Low Oxidation State Heavy P-Block Metal Compounds Supported by Di (amido) Chelating Ligands
R Schwamm - 2018 - openaccess.wgtn.ac.nz
The work presented in this thesis describes the synthesis and stabilisation of heavy p-block
elements (defined herein as being those with 5s/p and 6s/p valence electrons) in low …
elements (defined herein as being those with 5s/p and 6s/p valence electrons) in low …