Oxycarbenes have emerged as useful intermediates in synthetic chemistry. Compared to the
widely studied oxycarbene metal complexes bearing Group 6 metals, the synthetic and …

Acylsilanes have been utilized in various transformations for the synthesis of functionalized
organosilicon derivatives due to their importance in medicinal and materials science. This …

Although the synthesis of common cyclopropenes has been well studied, the access to
cyclopropenols is rather limited. Herein, we report the first synthesis of α‐trifluoromethylated …

Visible-light-driven organic photochemical reactions have attracted substantial attention
from the synthetic community. Typically, catalytic quantities of photosensitizers, such as …

Visible light induced singlet nucleophilic carbenes undergo rapid [2+ 1]-cycloaddition with
tethered olefins to afford unique bicyclo [3.1. 0] hexane and bicyclo [4.1. 0] heptane …

Light‐mediated coupling of acylsilanes with indoles is reported. This photo click reaction
occurs under mild conditions (415 nm) mostly in quantitative yield and provides stable …

Over fifty years ago, the 1, 2‐rearrangement of acylsilanes was first described by Adrian
Brook and co‐workers. This rearrangement (now termed the Brook rearrangement) yields …

Cyclopropanes are one of the most important strained rings existing in various
pharmaceutical products and secondary metabolites. They are also widely used in total …

Visible-light-driven functionalization of various organic systems has proved to be extremely
successful and reached an impressive level of sophistication as well as efficiency in the last …

A novel methodology for in situ generation of Fischer-type metal–carbene complexes was
developed. Photoirradiation to a mixture of an acylsilane and a cationic copper complex …