Phosphorolytic Reactivity of o-Iodosylcarboxylates and Related Nucleophiles

H Morales-Rojas, RA Moss - Chemical reviews, 2002 - ACS Publications
The discovery of the acute toxicity of various pentavalent organophosphorus compounds
toward living species led to the development, industrial production, and widespread use of …

Aqueous solutions of transition metal containing micelles

PC Griffiths, IA Fallis, T Tatchell, L Bushby… - Advances in colloid and …, 2008 - Elsevier
Incorporation of d-or f-block metals into ligand systems that renders a metal complex surface-
active or drives its partitioning into surfactant phases enables the localisation of chemical …

Evidence of enhanced reactivity of DAAP nucleophiles toward dephosphorylation and deacylation reactions in cationic Gemini micellar media

S Bhattacharya, VP Kumar - The Journal of Organic Chemistry, 2004 - ACS Publications
4, 4 '-(Dialkylamino) pyridine (DAAP)-based compounds 1− 4 catalytically cleave
hydrophobic organophosphate and carboxylate esters in various host micellar aggregates at …

A supramolecular catalyst based on sodium alginate and viologen calix [4] resorcinol for the room temperature hydrolysis of paraoxon

R Kashapov, Y Razuvayeva, A Ziganshina… - International Journal of …, 2024 - Elsevier
Abstract Properties of paraoxon, such as poor water solubility, low rate of natural
decomposition, ability to accumulate in soil and wastewater, lead to the fact that paraoxon is …

Metal-promoted hydrolysis of bis (p-nitrophenyl) phosphate by trivalent manganese complexes with Schiff base ligands in Gemini micellar solution

W Jiang, B Xu, Q Lin, J Li, F Liu, X Zeng… - Colloids and Surfaces A …, 2008 - Elsevier
Two crowned Schiff base manganese (III) complexes (MnL2Cl, L= L1, L2) were used to
catalyze the hydrolysis of bis (p-nitrophenyl) phosphate (BNPP) in Gemini surfactants [bis …

Catalysis of Phosphate Triester Hydrolysis by Micelles of Hexadecyltrimethylammonium anti-Pyruvaldehyde 1-Oximate

S Couderc, J Toullec - Langmuir, 2001 - ACS Publications
The hydrolysis reactions of 4-nitrophenyl diphenyl phosphate, 4-nitrophenyl di-4-tolyl
phosphate, and diethyl 4-nitrophenyl phosphate (paraoxon) have been studied in …

Substrate specific nanoreactors based on pyrimidine-containing amphiphiles of various structures for cleavage of phosphonates

DR Gabdrakhamanov, DA Samarkina… - … , Sulfur, and Silicon …, 2016 - Taylor & Francis
The series of novel pyrimidine-containing amphiphiles were examined as catalysts for
cleavage of phosphonates having various hydrophobicities. Kinetic data showed marked …

Metallosurfactants of Cu (II) and Fe (III) complexes as catalysts for the destruction of paraoxon

AA Hafiz - Journal of surfactants and detergents, 2005 - Wiley Online Library
Two micellized Cu (II) and Fe (III) ion complexes of octadecyl diethylene tri‐1‐amide are
used as nucleophilic reagents in the cleavage of the phosphate ester paraoxon. These …

Functional organic–inorganic colloids modified by iodoxybenzoic acid

L Bromberg, H Zhang, TA Hatton - Chemistry of Materials, 2008 - ACS Publications
A simple strategy for the modification of polymers having hydroxyl or amino groups on their
surfaces by o-iodoxybenzoyl (IBX) groups is described. The synthetic route involves …

Degradation of a VX Analogue: First Organometallic Reagent to Promote Phosphonothioate Hydrolysis Through Selective P− S Bond Scission

LY Kuo, TT Adint, AE Akagi, L Zakharov - Organometallics, 2008 - ACS Publications
We report the first case of a metal complex that degrades a neurotoxin mimic under
extremely mild conditions (pH 6.8, room temperature). The metallocene bis (η5 …