Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Porphyrin molecules are a widely exploited biochemical moiety, with uses in medicinal
chemistry, sensing and materials science. The shape of porphyrins, as an aromatic unit, is …

Abstract Transition-metal-catalysed, non-enzymatic transformations of C–H and C= C bonds
to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable …

Enantioselective transition metal catalysis is an area very much at the forefront of
contemporary synthetic research. The development of processes that enable the efficient …

Discovered as organometallic curiosities in the 1970s, carbene radicals have become a
staple in modern-day homogeneous catalysis. Carbene radicals exhibit nucleophilic radical …

Aromatic tertiary amines are one of the most important classes of organic compounds in
organic chemistry and drug discovery. It is difficult to efficiently construct tertiary amines from …

Nickel PyBox catalysts promote nucleophilic cyclopropanation reactions using CH2Cl2 as a
methylene source and Mn as a stoichiometric reductant. The substrate scope includes a …

Cyclopropanes are structural motifs that are widely present in natural products and bioactive
molecules, and they are also tremendously useful building blocks in synthetic organic …

Organocobalt (III) complexes (R-CoIII), defined as cobalt complexes featuring a carbon–
cobalt bond, are largely used to produce carbon-centered radicals by homolytic cleavage of …