Stability and reactivity: positive and negative aspects for nanoparticle processing

L Xu, HW Liang, Y Yang, SH Yu - Chemical reviews, 2018 - ACS Publications
Nanoparticles exist far from the equilibrium state due to their high surface energy.
Nanoparticles are therefore extremely unstable and easily change themselves or react with …

Cation exchange on the nanoscale: an emerging technique for new material synthesis, device fabrication, and chemical sensing

JB Rivest, PK Jain - Chemical Society Reviews, 2013 - pubs.rsc.org
Cation exchange is an age-old technique for the chemical conversion of liquids or extended
solids by place-exchanging the cations in an ionic material with a different set of cations. The …

Cation exchange: a versatile tool for nanomaterials synthesis

BJ Beberwyck, Y Surendranath… - The Journal of Physical …, 2013 - ACS Publications
The development of nanomaterials for next generation photonic, optoelectronic, and
catalytic applications requires a robust synthetic toolkit for systematically tuning composition …

Narrow bandgap colloidal metal chalcogenide quantum dots: synthetic methods, heterostructures, assemblies, electronic and infrared optical properties

SV Kershaw, AS Susha, AL Rogach - Chemical Society Reviews, 2013 - pubs.rsc.org
The chemistry, material processing and fundamental understanding of colloidal
semiconductor nanocrystals (quantum dots) are advancing at an astounding rate, bringing …

Highly luminescent InP/GaP/ZnS nanocrystals and their application to white light-emitting diodes

S Kim, T Kim, M Kang, SK Kwak, TW Yoo… - Journal of the …, 2012 - ACS Publications
Highly stable and luminescent InP/GaP/ZnS QDs with a maximum quantum yield of 85%
were synthesized by in situ method. The GaP shell rendered passivation of the surface and …

Accelerated development of colloidal nanomaterials enabled by modular microfluidic reactors: toward autonomous robotic experimentation

AA Volk, RW Epps, M Abolhasani - Advanced Materials, 2021 - Wiley Online Library
In recent years, microfluidic technologies have emerged as a powerful approach for the
advanced synthesis and rapid optimization of various solution‐processed nanomaterials …

CuInS 2/ZnS core/shell quantum dots by cation exchange and their blue-shifted photoluminescence

J Park, SW Kim - Journal of Materials Chemistry, 2011 - pubs.rsc.org
Highly luminescent CuInS2/ZnS (CIS/ZnS) core/shell quantum dots with a quantum yield of
65% were synthesized by a cation exchange reaction. Similar sized CIS cores and CIS/ZnS …

Selective facet reactivity during cation exchange in cadmium sulfide nanorods

B Sadtler, DO Demchenko, H Zheng… - Journal of the …, 2009 - ACS Publications
The partial transformation of ionic nanocrystals through cation exchange has been used to
synthesize nanocrystal heterostructures. We demonstrate that the selectivity for cation …

Cu vacancies boost cation exchange reactions in copper selenide nanocrystals

V Lesnyak, R Brescia, GC Messina… - Journal of the American …, 2015 - ACS Publications
We have investigated cation exchange reactions in copper selenide nanocrystals using two
different divalent ions as guest cations (Zn2+ and Cd2+) and comparing the reactivity of …

Combinatorial approaches for developing upconverting nanomaterials: high-throughput screening, modeling, and applications

EM Chan - Chemical Society Reviews, 2015 - pubs.rsc.org
Colloidal nanoparticles doped with lanthanide ions can upconvert near-infrared light to
visible frequencies, enabling the application of such materials to biological imaging and …