[HTML][HTML] Recent progress of catalysts for synthesis of cyclic carbonates from CO2 and epoxides

T Yan, H Liu, ZX Zeng, WG Pan - Journal of CO2 Utilization, 2023 - Elsevier
With the continuous emission of greenhouse gases, the rational transformation and
utilization of CO 2 is particularly important. Cyclic carbonates are a kind of versatile …

Organocatalyzed coupling of carbon dioxide with epoxides for the synthesis of cyclic carbonates: catalyst design and mechanistic studies

M Alves, B Grignard, R Méreau, C Jerome… - Catalysis Science & …, 2017 - pubs.rsc.org
The coupling of carbon dioxide (CO2) with epoxides with the formation of cyclic carbonates
is a highly attractive 100% atom economic reaction. It represents a greener and safer …

Imidazolium Ionic Liquids, Imidazolylidene Heterocyclic Carbenes, and Zeolitic Imidazolate Frameworks for CO2 Capture and Photochemical Reduction

S Wang, X Wang - Angewandte Chemie International Edition, 2016 - Wiley Online Library
Imidazolium ionic liquids (ILs), imidazolylidene N‐heterocyclic carbenes (NHCs), and
zeolitic imidazolate frameworks (ZIFs) are imidazolate motifs which have been extensively …

A DFT Study on the Mechanism of the Cycloaddition Reaction of CO2 to Epoxides Catalyzed by Zn(Salphen) Complexes

F Castro‐Gómez, G Salassa… - Chemistry–A European …, 2013 - Wiley Online Library
The reaction mechanism for the Zn (salphen)/NBu4X (X= Br, I) mediated cycloaddition of
CO2 to a series of epoxides, affording five‐membered cyclic carbonate products has been …

Recent Developments in the Synthesis of Cyclic Carbonates from Epoxides and CO2

H Büttner, L Longwitz, J Steinbauer, C Wulf… - … of Carbon Dioxide, 2018 - Springer
The use of CO 2 as a C1 building block will be of essential importance in the future. In this
context the synthesis of cyclic carbonates from epoxides and CO 2 gained great attention …

A refinement of everyday thinking: the energetic span model for kinetic assessment of catalytic cycles

S Kozuch - Wiley Interdisciplinary Reviews: Computational …, 2012 - Wiley Online Library
The energetic span model is a bridge connecting the kinetic outcome of experimental and
theoretical catalysis. It proves the utility of working with Gibbs energies (E‐representation) …

N-Heterocyclic Carbene Moiety in Highly Porous Organic Hollow Nanofibers for Efficient CO2 Conversions: A Comparative Experimental and Theoretical Study

S Bhattacharjee, A Tripathi, R Chatterjee, R Thapa… - ACS …, 2024 - ACS Publications
Global warming and climate change are two severe environmental dangers brought on by
the steady rise in the carbon dioxide (CO2) concentration in the atmosphere. Thus, in order …

Recent Advances in Carbon Dioxide Capture, Fixation, and Activation by using N‐Heterocyclic Carbenes

L Yang, H Wang - ChemSusChem, 2014 - Wiley Online Library
In the last two decades, CO2 emission has caused a lot of environmental problems. To
mitigate the concentration of CO2 in the atmosphere, various strategies have been …

[HTML][HTML] Recent advances in the coupling of CO2 and epoxides into cyclic carbonates under halogen-free condition

F Zhang, Y Wang, X Zhang, X Zhang, H Liu… - Green Chemical …, 2020 - Elsevier
The chemical transformation of CO 2 and epoxides into cyclic carbonates has been
receiving much attention and is one of the successful examples for CO 2 utilization as …

Recent advances in metal-free catalysts for the synthesis of cyclic carbonates from CO2 and epoxides

DH Lan, N Fan, Y Wang, X Gao, P Zhang… - Chinese Journal of …, 2016 - Elsevier
The aim of “green chemistry” and “atom economy” is to utilize carbon dioxide and replace
harmful reactants such as CO and phosgene for the production of cyclic carbonates. In this …