Ultrahigh molecular weight polyethylene: Catalysis, structure, properties, processing and applications

K Patel, SH Chikkali, S Sivaram - Progress in polymer science, 2020 - Elsevier
Ultrahigh molecular weight polyethylene (UHMWPE) belongs to an emerging class of high-
performance specialty polymers with a unique set of properties and applications. The field …

From multisite polymerization catalysis to sustainable materials and all-polyolefin composites

M Stürzel, S Mihan, R Mülhaupt - Chemical reviews, 2016 - ACS Publications
Since the pioneering advances of Karl Ziegler and Giulio Natta during the early 1950s, a
continuing series of breakthroughs in research and industrial innovations have greatly …

Nascent disentangled UHMWPE: Origin, synthesis, processing, performances and applications

SL Wu, J Qiao, J Guan, HM Chen, T Wang… - European Polymer …, 2023 - Elsevier
The advent of nascent d-UHMWPE overcomes the intrinsic melting defects and crystal
boundaries within the commercial UHMWPE (C-UHMWPE) based products, and opens the …

Post-metallocene catalysts for the synthesis of ultrahigh molecular weight polyethylene: Recent advances

AA Antonov, KP Bryliakov - European Polymer Journal, 2021 - Elsevier
This review summarizes the progress of transition metal catalyzed ethylene polymerization
to ultra-high molecular weight polyethylene (UHMWPE), focusing on the catalytic activities of …

Tailoring hydrocarbon polymers and all‐hydrocarbon composites for circular economy

T Hees, F Zhong, M Stürzel… - Macromolecular rapid …, 2019 - Wiley Online Library
The world population will rapidly grow from 7 to 9 billion by 2050 and this will parallel a
surging annual plastics consumption from today's 350 million tons to well beyond 1 billion …

Influence of Molecular Weight and Entanglement Density on the Creep Response of the Uniaxially Drawn Tapes of dis-UHMWPE

RP Gote, J van der Eem, J Zhao, S Lolage… - …, 2023 - ACS Publications
Polyethylene with a molecular weight greater than a million g/mol, is of increasing
commercial interest because it provides a route to make fibers and films that have …

Unprecedented mechanical properties in linear UHMWPE using a heterogeneous catalytic system

RP Gote, D Romano, J van der Eem, J Zhao… - …, 2022 - ACS Publications
Several homogeneous postmetallocene complexes are known to produce weakly entangled
ultrahigh-molecular-weight polyethylene (disentangled UHMWPE) under controlled …

Access to disentangled ultrahigh molecular weight polyethylene via a binuclear synergic effect

Z Zhang, X Kang, Y Jiang, Z Cai, S Li… - Angewandte Chemie …, 2023 - Wiley Online Library
Disentangled ultrahigh molecular weight polyethylene (dis‐UHMWPE) has excellent
processability but can be achieved under extreme conditions. Herein, we report ethylene …

A series of green oxovanadium (IV) precatalysts with O, N and S donor ligands in a sustainable olefins oligomerization process

M Urbaniak, K Pobłocki, P Kowalczyk, K Kramkowski… - Molecules, 2022 - mdpi.com
Designing catalyst systems based on transition metal ions and activators using the
principles of green chemistry is a fundamental research goal of scientists due to the …

Entanglement formation mechanism in the POSS modified heterogeneous Ziegler–Natta catalysts

Y Chen, P Liang, Z Yue, W Li, C Dong, B Jiang… - …, 2019 - ACS Publications
Chain entanglement was very important for adjusting the processability and mechanical
property of nascent ultrahigh molecular weight polyethylene (UHMWPE). So far, it is still a …