Thermal Stability and Outgassing Behaviors of High‐nickel Cathodes in Lithium‐ion Batteries

Z Cui, A Manthiram - Angewandte Chemie International Edition, 2023 - Wiley Online Library
LiNiO2‐based high‐nickel layered oxide cathodes are regarded as promising cathode
materials for high‐energy‐density automotive lithium batteries. Most of the attention thus far …

Degradation mechanisms and mitigation strategies of nickel-rich NMC-based lithium-ion batteries

T Li, XZ Yuan, L Zhang, D Song, K Shi… - Electrochemical Energy …, 2020 - Springer
The demand for lithium-ion batteries (LIBs) with high mass-specific capacities, high rate
capabilities and long-term cyclabilities is driving the research and development of LIBs with …

Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen

K Luo, MR Roberts, R Hao, N Guerrini, DM Pickup… - Nature …, 2016 - nature.com
During the charging and discharging of lithium-ion-battery cathodes through the de-and
reintercalation of lithium ions, electroneutrality is maintained by transition-metal redox …

A review of Ni-based layered oxides for rechargeable Li-ion batteries

J Xu, F Lin, MM Doeff, W Tong - Journal of Materials Chemistry A, 2017 - pubs.rsc.org
The portable electronic market, vehicle electrification (electric vehicles or EVs) and grid
electricity storage impose strict performance requirements on Li-ion batteries, the energy …

Li-rich layered oxide cathodes for next-generation Li-ion batteries: chances and challenges

P Rozier, JM Tarascon - Journal of The Electrochemical Society, 2015 - iopscience.iop.org
Since their commercialization Li-ion batteries have relied on the use of layered oxides (LiMO
2) as positive electrodes. Over the years, via skilful chemical substitution their performances …

Surface and subsurface reactions of lithium transition metal oxide cathode materials: an overview of the fundamental origins and remedying approaches

B Xiao, X Sun - Advanced Energy Materials, 2018 - Wiley Online Library
Lithium‐ion batteries (LIBs) have become one of the most prevailing techniques for
rechargeable batteries. Lithium transition metal oxides are prevalent cathode materials …

The truth about the 1st cycle Coulombic efficiency of LiNi 1/3 Co 1/3 Mn 1/3 O 2 (NCM) cathodes

J Kasnatscheew, M Evertz, B Streipert… - Physical chemistry …, 2016 - pubs.rsc.org
The 1st cycle Coulombic efficiency (CE) of LiNi1/3Co1/3Mn1/3O2 (NCM) at 4.6 V vs. Li/Li+
has been extensively investigated in NCM/Li half cells. It could be proven that the major part …

Electrochemo‐mechanical stresses and their measurements in sulfide‐based all‐solid‐state batteries: a review

J Gu, Z Liang, J Shi, Y Yang - Advanced Energy Materials, 2023 - Wiley Online Library
Sulfide‐based all‐solid‐state batteries (ASSBs) are one of the most promising energy
storage devices due to their high energy density and good safety. However, due to the …

Twin Boundaries Contribute to The First Cycle Irreversibility of LiNiO2

H Nguyen, R Silverstein, A Zaveri, W Cui… - Advanced Functional …, 2023 - Wiley Online Library
LiNiO2 remains a target for layered oxide Li‐ion cathode development as it can theoretically
deliver the highest energy density of this materials class. In practice, LiNiO2 suffers from …

Activation Mechanism of LiNi0.80Co0.15Al0.05O2: Surface and Bulk Operando Electrochemical, Differential Electrochemical Mass Spectrometry, and X-ray …

R Robert, C Bunzli, EJ Berg, P Novák - Chemistry of Materials, 2015 - ACS Publications
The lithium (de)-insertion mechanism from LiNi0. 80Co0. 15Al0. 05O2 (NCA) has been
investigated by means of combined electrochemical analysis, operando differential …