Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy
are of primary importance in physics, chemistry and biology. Our literature overview …

Mixed-valence dilanthanide complexes of the type (CpiPr5) 2Ln2I3 (CpiPr5=
pentaisopropylcyclopentadienyl; Ln= Gd, Tb, Dy) featuring a direct Ln–Ln σ-bonding …

A series of linear sandwich single-ion magnets containing [Er (COT)]+ fragment were
selected to probe the magneto-structural correlations using ab initio methods. For prolate …

Progress in the synthesis, design, and characterisation of single-molecule magnets (SMMs)
has expanded dramatically from curiosity driven beginnings to molecules that retain …

Complete active space self-consistent field (CASSCF) combined with restricted active space
spin interaction with spin–orbit coupling (RASSI-SO) was used to probe why single-ion …

Using dianionic metallole ligands (silole or germole) and the cyclooctatetraendiide dianion,
heteroleptic lanthanide multi-decker complexes have been prepared. Due to the heteroatom …

Abstract Solvation of [(CNT) Ln (η8‐COT)](Ln= La, Ce, Nd, Tb, Er; CNT= cyclononatetraenyl,
ie, C9H9−; COT= cyclooctatetraendiid, ie, C8H82−) complexes with tetrahydrofuran (THF) …

Magnetic molecules known as molecular nanomagnets (MNMs) may be the key to ultra-high
density data storage. Thus, novel strategies on how to design MNMs are desirable. Here …

Abstract Single-molecule magnets (SMMs), which can exhibit slow magnetization relaxation
and bulk-magnet-like hysteresis of purely molecular origin, are promising candidates for …