The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

The first now-named Stille reaction was published 38 years ago, and the last comprehensive
revision of this catalysis was in 2004. Since then, the knowledge of the different steps of the …

The activation of Csingle bondX bonds in homogeneous systems is a relevant topic in
relation to important catalytic industrial processes involving organic substrates and …

The C–N cross-coupling chemistry intensely developed since the late 1990s has supplied
synthesists with an overwhelming number of methods to effectively combine carbon and …

The seminal contributions by Sonogashira, Cassar and Heck in mid 1970s on Pd/Cu-and Pd-
catalysed (copper-free) coupling of acetylenes with aryl or vinyl halides have evolved in …

A DFT study of R− R reductive elimination (R= Me, Ph, vinyl) in plausible intermediates of Pd-
catalyzed processes is reported. These include the square-planar tetracoordinated systems …

The Suzuki− Miyaura cross-coupling reaction using PMe3, PPh3, and P t Bu3 as ligands
was studied theoretically with accurate density functional theory (DFT) methods and the …

DFT calculations have been used to explore the full catalytic cycle of the Suzuki–Miyaura
coupling between PhBr and PhB (OH) 3− with four different palladium monophosphine …

The manifold of reaction pathways for the oxidative addition of phenyl bromide and phenyl
chloride substrates to phosphine-modified palladium (0) complexes has been investigated …

Reversible leaching of palladium nanoparticles occurs in a variety of catalytic reactions
including cross-couplings, amination, the Heck reaction, etc. It is complemented by capturing …