Iodine in organic synthesis

AK Banerjee, W Vera, H Mora, MS Laya, L Bedoya… - 2006 - nopr.niscpr.res.in
Commercially available iodine has played an important role in organic synthesis. This
review discusses the versatile uses of iodine in different chemical transformations …

[HTML][HTML] Hypervalent iodine compounds for anti-Markovnikov-type iodo-oxyimidation of vinylarenes

IB Krylov, SA Paveliev, MA Syroeshkin… - Beilstein journal of …, 2018 - beilstein-journals.org
The iodo-oxyimidation of styrenes with the N-hydroxyimide/I 2/hypervalent iodine oxidant
system was proposed. Among the examined hypervalent iodine oxidants (PIDA, PIFA, IBX …

Oxone-Mediated Regioselective Oxy-iodination of 1-Aryl/Alkyl Butadienes Using TBAI

DA Gorve, RA Fernandes - The Journal of Organic Chemistry, 2024 - ACS Publications
A simple, mild, and environmentally benign regioselective oxy-iodination of 1-aryl/alkyl
butadienes has been developed. While styrenes have been explored previously, this work …

Trichloroisocyanuric acid: an alternate green route for the transformation of alkenes into epoxides

M Wengert, AM Sanseverino, M Mattos - Journal of the Brazilian …, 2002 - SciELO Brasil
SciELO - Brasil - Trichloroisocyanuric Acid: An Alternate Green Route for the Transformation of
Alkenes into Epoxides Trichloroisocyanuric Acid: An Alternate Green Route for the …

Trichloroisocyanuric acid as a cohalogenating reagent: An efficient transformation of alkenes into chlorohydrins, β-chloroethers and β-chloroacetates

GF Mendonça, AM Sanseverino, MCS de Mattos - Synthesis, 2003 - thieme-connect.com
The preparation of diverse β-chloroethers, β-chloroacetates, and chlorohydrins is efficiently
achieved under mild conditions by reaction of alkenes with trichloroisocyanuric acid (0.34 …

Combination of NH 2 OH· HCl and NaIO 4: an effective reagent for molecular iodine-free regioselective 1, 2-difunctionalization of olefins and easy access of terminal …

N Chakraborty, S Santra, SK Kundu, A Hajra… - RSC …, 2015 - pubs.rsc.org
We have demonstrated a new application of our oxidizing reagent, a combination of
NH2OH· HCl and NaIO4, in the first generalized regioselective 1, 2-difunctionalization of …

Triiodoisocyanuric acid: a new and convenient reagent for regioselective coiodination of alkenes and enolethers with oxygenated nucleophiles

RS Ribeiro, PM Esteves, MCS de Mattos - Tetrahedron letters, 2007 - Elsevier
The reaction of triiodoisocyanuric acid (prepared from I2 and trichloroisocyanuric acid in
90% yield) with alkenes in the presence of oxygenated nucleophilic solvents (alcohols …

trans-Diastereoselective Syntheses of γ-Lactones by Visible Light-Iodine-Mediated Carboesterification of Alkenes

S Maejima, E Yamaguchi, A Itoh - ACS omega, 2019 - ACS Publications
This study aims to develop an intermolecular lactonization reaction of alkenes with
carbonyls mediated by visible light and molecular iodine. The one-step reaction involved the …

Selenium-catalyzed iodohydrin formation from alkenes

I Carrera, MC Brovetto, GA Seoane - Tetrahedron letters, 2006 - Elsevier
A new simple method for catalyzed iodohydroxylation of alkenes using stoichiometric
amounts of water is described. The iodohydrins were prepared in good yields from the …

EPZ-10 catalyzed regioselective transformation of alkenes into β-iodo ethers, iodohydrins and 2-iodomethyl-2, 3-dihydrobenzofurans

A Vishal - Green Chemistry, 2002 - pubs.rsc.org
An efficient method for the regioselective synthesis of β-iodo ethers and iodohydrines from
styrene, indene and dihydronaphthalene in presence of EPZ-10R has been presented …