Luminescent single-molecule magnets based on lanthanides: Design strategies, recent advances and magneto-luminescent studies
Incorporation of two characters into one molecular entity is an effective way to afford
bifunctional molecule-based materials. Lanthanides serve as a group of preferable …
bifunctional molecule-based materials. Lanthanides serve as a group of preferable …
Dual self-healing effects of salicylate intercalated MgAlY-LDHs film in-situ grown on the micro-arc oxidation coating on AZ31 alloys
Micro-arc oxidation (MAO) coatings only provide the passive protection of common Mg
alloys (AZ31), especially causing severe localized corrosion under accidental damage …
alloys (AZ31), especially causing severe localized corrosion under accidental damage …
A Family of Lanthanide Hydroxo Carboxylates with 1D Polymeric Topology and Ln4 Butterfly Core Exhibits Switchable Supramolecular Arrangement
The unique family of coordination polymers [Ln4 (OH) 2 (piv) 10 (H2O) 2]∞ of 11
lanthanides (Ln= La–Er) has been prepared by a simple solution method based on …
lanthanides (Ln= La–Er) has been prepared by a simple solution method based on …
Influence of magnetic interactions and single-ion anisotropy on magnetic relaxation within a family of tetranuclear dysprosium complexes
J Lu, YQ Zhang, XL Li, M Guo, J Wu, L Zhao… - Inorganic …, 2019 - ACS Publications
Six tetranuclear DyIII complexes [Dy4 (L) 2 (CH3OH) 3 (NO3) 3]· 3NO3· 2H2O (1a),[Dy4 (L) 2
(CH3OH) 2 (SCN) 4 (OCH3) 2]· 2CH3OH· 2H2O (1b),{[Dy4 (L) 2 (CH3OH)(SCN) 6 …
(CH3OH) 2 (SCN) 4 (OCH3) 2]· 2CH3OH· 2H2O (1b),{[Dy4 (L) 2 (CH3OH)(SCN) 6 …
Single-Molecule-Magnet Behavior in a [2 × 2] Grid DyIII4 Cluster and a Dysprosium-Doped YIII4 Cluster
Thanks to the MeCN hydrolysis in situ reaction, a [2× 2] square grid DyIII4 cluster based on a
polypyridyl triazolate ligand,[Dy4 (OH) 2 (bpt) 4 (NO3) 4 (OAc) 2](1), was separated …
polypyridyl triazolate ligand,[Dy4 (OH) 2 (bpt) 4 (NO3) 4 (OAc) 2](1), was separated …
Macrocycle supported dimetallic lanthanide complexes with slow magnetic relaxation in Dy 2 analogues
FX Shen, K Pramanik, P Brandão, YQ Zhang… - Dalton …, 2020 - pubs.rsc.org
Six dimetallic lanthanide complexes,[Ln2 (L′)(acac) 4](1Dy–3Gd)(Ln= Dy (1Dy), Tb (2Tb)
and Gd (3Gd)) and [Ln2 (L′)(tfac) 4](4Dy–6Gd)(Ln= Dy (4Dy), Tb (5Tb) and Gd …
and Gd (3Gd)) and [Ln2 (L′)(tfac) 4](4Dy–6Gd)(Ln= Dy (4Dy), Tb (5Tb) and Gd …
Tetranuclear and pentanuclear compounds of the rare-earth metals: synthesis and magnetism
The Schiff-base proligand 4-tert-butyl-2, 6-bis-[(2-hydroxy-phenylimino) methyl] phenol
(H3L) was prepared in situ from 4-tert-butyl-2, 6-diformylphenol and 2-aminophenol. The …
(H3L) was prepared in situ from 4-tert-butyl-2, 6-diformylphenol and 2-aminophenol. The …
A family of dinuclear lanthanide (III) complexes from the use of a tridentate Schiff base
The use of N-salicylidene-o-aminophenol (H2saph) in 4f-metal chemistry has led to the
isolation of seven new isostructural lanthanide (III)[LnIII] complexes. More specifically the Ln …
isolation of seven new isostructural lanthanide (III)[LnIII] complexes. More specifically the Ln …
Multiple magnetic relaxation processes, magnetocaloric effect and fluorescence properties of rhombus-shaped tetranuclear rare earth complexes
HL Gao, L Jiang, S Liu, HY Shen, WM Wang… - Dalton …, 2016 - pubs.rsc.org
Seven new tetranuclear rare earth (RE) complexes [RE4 (acac) 4L6 (μ3-OH) 2](HL= 5-(4-
fluorobenzylidene)-8-hydroxylquinoline; acac= acetylacetonate; RE= Y (1), Eu (2), Gd (3), Tb …
fluorobenzylidene)-8-hydroxylquinoline; acac= acetylacetonate; RE= Y (1), Eu (2), Gd (3), Tb …
Observation of Slow Relaxation and Single‐Molecule Toroidal Behavior in a Family of Butterfly‐Shaped Ln4 Complexes
A family of five isostructural butterfly complexes with a tetranuclear [Ln4] core of the general
formula [Ln4 (LH) 2 (μ2‐η1η1Piv)(η2‐Piv)(μ3‐OH) 2]⋅ x H2O⋅ y MeOH⋅ z CHCl3 (1: Ln …
formula [Ln4 (LH) 2 (μ2‐η1η1Piv)(η2‐Piv)(μ3‐OH) 2]⋅ x H2O⋅ y MeOH⋅ z CHCl3 (1: Ln …