Isolated transition metal clusters have been established as useful models for extended metal
surfaces or deposited metal particles, to improve the understanding of their surface …

The study of reactions relevant to heterogeneous catalysis on the surface of well-defined
metal clusters with full control over the number of consituent atoms and elemental …

Due to the extraordinary catalytic activity in redox reactions, the noble metal, rhodium, has
substantial industrial and laboratory applications in the production of value-added …

Transition‐metal clusters have long been proposed as model systems to study
heterogeneous catalysts. In this Concept article we show how advanced spectroscopic …

n+(n= 6–12) are investigated by comparison of experimental far-infrared multiple photon
dissociation spectra with spectra calculated using density functional theory. The clusters are …

The decomposition of nitric oxide on small charged rhodium clusters Rh n+/-(6< n< 30) has
been investigated by Fourier transform ion cyclotron resonance mass spectrometry. For both …

Adsorption and desorption of N2 molecules onto cationic Ta and Rh clusters in the gas
phase were investigated in the temperature range of 300–1000 K by using thermal …

In this study, mixed carbonyl and nitrous oxide complexes with Rh+ were studied by mass-
selective infrared photodissociation spectroscopy in a molecular beam. The infrared spectra …

Far-and mid-infrared multiple photon dissociation spectroscopy has been employed to study
both the structure and surface reactivity of isolated cationic rhodium clusters with surface …

This paper presents a combined IR photo dissociation (IR-PD) spectroscopic and DFT
computational study of cold Rhodium cluster N 2 adsorbate complexes,[Rh i (N 2) m]+=(i, m) …