Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

This Review describes the application of nitroxides to synthesis and polymer chemistry. The
synthesis and physical properties of nitroxides are discussed first. The largest section …

We report the development of a new aminoxyl radical catalyst, CHAMPO, for the
electrochemical diazidation of alkenes. Mediated by an anodically generated charge …

The organic nitroxyl radical, TEMPO (2, 2, 6, 6-tetramethylpiperidine-N-oxyl), finds a variety
of industrial applications for chemical transformations. Because of economic and …

Over the past decade, the effectiveness of i-PrMgCl· LiCl has been constantly highlighted by
a number of research groups. Its enhanced nucleophilicity brings prosperity to highly …

Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in
the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain …

The Pd-catalyzed Sonogashira reaction is a powerful method for the formation of Csp2–Csp
bonds and has found application in a wide variety of areas including medicinal chemistry …

The conversion–time data for 168 different Pd/Cu-catalyzed Sonogashira cross-coupling
reactions of five arylacetylenes (phenylacetylene; 1-ethynyl-2-ethylbenzene; 1-ethynyl-2, 4 …

The well-known Sonogashira reaction is one of the most commonly used methods for
installing alkyne moieties into (hetero) arenes molecules.[2] Recently, the direct alkynylation …