Macroelectrode voltammetry in toluene using a phosphonium–phosphate ionic liquid as the supporting electrolyte

NW Duffy, AM Bond - Electrochemistry communications, 2006 - Elsevier
The ability of the ionic liquid trihexyl (tetradecyl) phosphonium tris (pentafluoroethyl)
trifluorophosphate (aph4. cph12) to act as an ionic conductor in toluene has been …

Physical chemical properties and kinetics of redox processes in water/soybean oil microemulsions

CRB Mendonça, CID Bica, EF Simó-Alfonso… - Journal of the Brazilian …, 2008 - SciELO Brasil
Water/oil microemulsions (w/o ME) constituted by water, soybean oil, SDS (sodium dodecyl
sulfate) and several short-chain alcohols were characterized from the viewpoint of its …

Influence of electrolyte concentration on coupled chemical reactions Part 1Reduction of CoII (salen) in aprotic solvents

D Pletcher, H Thompson - Journal of the Chemical Society, Faraday …, 1997 - pubs.rsc.org
The reduction of CoII (salen) has been investigated using Au microdisc electrodes in DMF
containing several electrolytes, concentrations in the range 0.1–100 mM. The kinetics of the …

Heterogeneous electron transfer and diffusivities of ferrocene/ferrocenium couple in toluene/phosphonium-based ionic liquid solutions

N Brinis, K Aoudia, L Chaal, B Saidani… - Journal of …, 2013 - Elsevier
The heterogeneous rate constant k0 of the ferrocene/ferrocenium (Fc/Fc+) redox couple and
the diffusivities (DFc and DFc+) of the two species were measured in a toluene/trihexyl …

Electrochemical detection of Cu (I) and Cu (II) in styrene media

K De Wael, P Westbroek, J De Strycker, E Gasana… - Microchemical …, 2004 - Elsevier
A method is described to detect Cu (II) and Cu (I) added as bromide simultaneously in
styrene solution containing tetrahexylammoniumperchloraat (THAP) as supporting …

Amperometric response of alcohols dissolved in high resistance hydrocarbon media at microelectrodes without supporting electrolyte

L Kiss, G Nagy, B Kovács - Electroanalysis, 2012 - Wiley Online Library
Narrow‐gap cells were fabricated for direct amperometric measurement of alcohol content in
liquid hydrocarbon mixtures. Their performance has been investigated using methanol …

Effect of the medium composition on the current of steady state voltammograms of neutral and charged species in dimethylformamide/toluene mixtures

MF Bento, MD Geraldo, MI Montenegro - Analytica chimica acta, 1999 - Elsevier
Steady state voltammetric currents of both neutral and charged species obtained at
microelectrodes are affected by the medium composition. Experiments carried out in N, N …

Kinetic Investigation of the Electrochemical Oxidation of Bis (benzene) chromium (0) in Diethyl ketone/N, N-Dimethylformamide

NG Tsierkezos - Journal of solution chemistry, 2008 - Springer
The cyclic voltametric technique utilizing a platinum working electrode was applied for the
investigation of the electrochemical oxidation of bis (benzene) chromium (0),(C 6 H 6) 2 Cr …

Electrochemical reduction of vinyl chloride on a Au/porous alumina plate/Pt electrode assembly in nonaqueous electrolytes: Toward the development of gas sensors

MC Chuang, MC Yang - Journal of applied electrochemistry, 2003 - Springer
A novel configuration consisting of one porous alumina plate, two electrodes sputtered on
both sides and an organic electrolyte, was developed to analyse in situ vinyl chloride in the …

Electroanalytical determination of styrene in acrylonitrile‐butadiene‐styrene copolymers

MD Geraldo, MI Montenegro - Electroanalysis, 1997 - Wiley Online Library
The analysis of residual styrene in terpolymers of acrylonitrile, butadiene and styrene (ABS)
by a rapid electroanalytical method is described. The sample is simply dissolved in N, N …