Hydrogen spillover as a promising strategy for boosting heterogeneous catalysis and hydrogen storage

M Li, W Yin, J Pan, Y Zhu, N Sun, X Zhang… - Chemical Engineering …, 2023 - Elsevier
Hydrogen spillover, a common active species migration phenomenon, has drawn
tremendous attention in the past few years. The spilled atomic hydrogen can not only …

[HTML][HTML] Magic of hydrogen spillover: Understanding and application

H Shen, H Li, Z Yang, C Li - Green Energy & Environment, 2022 - Elsevier
The hydrogen spillover effect (HSPE) plays an important role in heterogeneous catalysis
and hydrogen storage as an interfacial phenomenon, which facilitates the improvement of …

Spillover in heterogeneous catalysis: new insights and opportunities

M Xiong, Z Gao, Y Qin - ACS Catalysis, 2021 - ACS Publications
Spillover is a well-known phenomenon in heterogeneous catalysis and is involved in many
important reactions. The establishment of the spillover concept opened up a new research …

Dilute alloys based on Au, Ag, or Cu for efficient catalysis: from synthesis to active sites

JD Lee, JB Miller, AV Shneidman, L Sun… - Chemical …, 2022 - ACS Publications
The development of new catalyst materials for energy-efficient chemical synthesis is critical
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …

A review on catalytic hydrodeoxygenation of lignin to transportation fuels by using nickel-based catalysts

MM Ambursa, JC Juan, Y Yahaya… - … and Sustainable Energy …, 2021 - Elsevier
Lignin-derived bio-oil required upgrades to reduce its oxygen functionalities to produce high
quality liquid fuel that is comparable to those of petroleum source. Hydrodeoxygenation is a …

In situ tuning of electronic structure of catalysts using controllable hydrogen spillover for enhanced selectivity

M Xiong, Z Gao, P Zhao, G Wang, W Yan… - Nature …, 2020 - nature.com
In situ tuning of the electronic structure of active sites is a long-standing challenge. Herein,
we propose a strategy by controlling the hydrogen spillover distance to in situ tune the …

Trimetallic Cu–Ni–Zn/H-ZSM-5 catalyst for the one-pot conversion of levulinic acid to high-yield 1, 4-pentanediol under mild conditions in an aqueous medium

N Karanwal, MG Sibi, MK Khan, AA Myint… - ACS …, 2021 - ACS Publications
The one-pot direct conversion of levulinic acid (LA) to 1, 4-pentanediol (1, 4-PDO) was
investigated over a trimetallic Zn-promoted Cu–Ni alloy on a H-ZSM-5 (Cu–Ni–Zn/H-ZSM-5) …

Synergism studies on alumina-supported copper-nickel catalysts towards furfural and 5-hydroxymethylfurfural hydrogenation

S Srivastava, GC Jadeja, J Parikh - Journal of Molecular Catalysis A …, 2017 - Elsevier
The structure of alumina-supported copper-nickel catalysts prepared by impregnation
method was studied by using a combination of various characterization techniques including …

Upgrading technologies and catalytic mechanisms for heteroatomic compounds from bio-oil–A review

C Zhao, C Hong, J Hu, Y Xing, W Ling, B Zhang… - Fuel, 2023 - Elsevier
This paper reviews the research progress of heteroatomic compound treatment technology
in bio-oil. Bio-oil fuels are expected to be a renewable energy source instead of fossil fuels …

Controlled hydrodeoxygenation of biobased ketones and aldehydes over an alloyed Pd–Zr catalyst under mild conditions

W Ding, H Li, R Zong, J Jiang… - … Sustainable Chemistry & …, 2021 - ACS Publications
The substitution of green hydrogen donors for replacing high-pressure H2 to achieve
biomass derived ketone and aldehyde hydrodeoxygenation (HDO) under mild conditions …